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- W4224291412 abstract "Ruthenium-based metallo-supramolecular polymers (Ru-MSPs) were synthesized by complexing Ru ions with 1,4-bis(1,10-phenanthrolin-5-yl)benzene ligands for heterogeneously catalytic transfer hydrogenation of carbonyl compounds with formate. The degree of polymerization and the local environment of Ru atoms in Ru-MSP were tailored by tuning the ligand/metal ratio and the synthesis temperature/period. The coordinatively-unsaturated Ru atoms are identified as the active centers in Ru-MSP for carbonyl reduction. Ru-MSP is much more active than Ru-based counterparts including its monomeric analogue, which is attributed to (1) the higher electron density in Ru atoms that facilitates the selective dehydrogenation of formate via C-H dissociation, and (2) the lower LUMO of ligand moieties that activates the carbonyl oxygen via Lewis acid-base interactions. Furthermore, Ru-MSP displays high reusability and capability of catalyzing a wide scope of carbonyl compounds. These findings demonstrate that the rationally-designed polymerization is a promising approach to heterogenize the catalytically active metal complexes with enhanced performance." @default.
- W4224291412 created "2022-04-26" @default.
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- W4224291412 date "2022-09-01" @default.
- W4224291412 modified "2023-10-18" @default.
- W4224291412 title "Rational synthesis of ruthenium-based metallo-supramolecular polymers as heterogeneous catalysts for catalytic transfer hydrogenation of carbonyl compounds" @default.
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- W4224291412 doi "https://doi.org/10.1016/j.apcatb.2022.121383" @default.
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