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- W4224309021 abstract "We disclose an iridium(III)-catalyzed regioselective B(4)-H allenylation of o-carboranes from o-carborane acids and propargyl carbonates under ball-milling conditions. This study sheds light on a novel method to accomplish regioselective B(4)-allenylation of o-carborane that cannot be realized through conventional solution-based reactions. Control experiments, including solution, neat, microwave, and high-temperature reactions, reveal that the B(4)-H allenylation of o-carborane is unique for ball-milling conditions." @default.
- W4224309021 created "2022-04-26" @default.
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- W4224309021 date "2022-04-25" @default.
- W4224309021 modified "2023-10-03" @default.
- W4224309021 title "Iridium(III)-Catalyzed Regioselective B(4)–H Allenylation of <i>o</i>-Carboranes by Ball Milling" @default.
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- W4224309021 doi "https://doi.org/10.1021/acs.orglett.2c00756" @default.
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