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• W4224852022 abstract "Herein, we report the metal-free hydration of pyridine-SF4-alkynes, under acidic conditions and with reaction durations ranging from 5 min to 10 h at room temperature, to synthesize pyridine-SF4-methyl ketones in yields of 59-93%. Further, we demonstrate the synthetic applications of the synthesized pyridine-SF4-methyl ketones, such as chlorination, NaBH4 reduction, Baeyer-Villiger oxidation, and the generation of enol-triflates. These compounds hold promise as useful building blocks in the syntheses of a wide range of SF4-containing drug candidates." @default.
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• W4224852022 date "2022-04-25" @default.
• W4224852022 modified "2023-09-24" @default.
• W4224852022 title "Regioselective Synthesis of Pyridine-SF₄-Methyl Ketones via Hydration of Pyridine-SF₄-Alkynes" @default.
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• W4224852022 doi "https://doi.org/10.1021/acs.orglett.2c00998" @default.
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