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- W4224880096 endingPage "136601" @default.
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- W4224880096 abstract "Permanently, heavy metal pollution and bacterial contamination have always caused a serious burden on the maintenance of ecological environment in the background of excessive industrial emissions and antibiotic abuse. Herein, a thiocarbonyl compound 7-(N,N-diethylamino)-4-trifluoromethyl-2-thiocoumarin named ThioCou35, has been put forward for tackling these two intractable points. The specific thiocarbonyl moiety on this donor-π-accepter electronic chemical structure endows this small molecule with intriguing optical properties and applicable functions. First, benefitting from the activated thiocarbonyl group, the small-molecule ThioCou35 provides dual discernable fluorescence lighting up channels (green and red) for the precise measurement of two environmentally unfriendly heavy metal ions (Hg2+ and Ag+) based on two different mechanisms. Probe ThioCou35 has been further employed for the evaluation of water quality and bioimaging of living bacteria. Furthermore, profited from the strong molecular absorption and significant fluorescence loss, the ThioCou35 is capable of intersystem crossing where substantial highly toxic reactive oxygen species is harvested when launched by visible light. Therefore, this controllable photosensitizer is suitable for the rapid killing of pathogenic bacteria, which presents a widespread germicidal potency beneficial to health caring. Promisingly, this heavy-atom-free and small-in-size molecule represents next-generation fluorescent materials devoting to environmental quality monitoring and human health caring." @default.
- W4224880096 created "2022-04-27" @default.
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- W4224880096 date "2022-09-01" @default.
- W4224880096 modified "2023-10-01" @default.
- W4224880096 title "Engineering of a multifunctional small molecule enables dual-channel fluorescence visualizing of environmental unamiable heavy metal ions as well as photoinactivation-based and ultra-efficient eliminating of human pathogens" @default.
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- W4224880096 doi "https://doi.org/10.1016/j.cej.2022.136601" @default.
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