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- W4224884312 endingPage "124896" @default.
- W4224884312 startingPage "124896" @default.
- W4224884312 abstract "Metal-ligand coordination was used to construct supramolecular elastomers with self-healing ability and excellent mechanical properties. In this study, novel iminocarboxyl-functionalized polysiloxanes (PDMS-Iminocarboxyl) was synthesized through amine-functionalized polysiloxanes (PDMS-NH2) with acrylic acid by aza-Michael addiction based on 1H NMR and FTIR spectroscopy. The incorporation of zinc ions into the PDMS-Iminocarboxyl as chemical crosslinks could essentially improve the thermal and mechanical properties because of highly dynamic Zn(II)-iminocarboxyl complexation. The stoichiometric ratio of [Zn2+]/[COOH] were determined by NMR titration. Furthermore, the presence of dynamic Zn(II)-iminocarboxyl equilibrium could allow a degree of strain sensitivity upon various stretching rates based on tensile experiments and rheological analysis. From the DMA and rheological analysis, modulus transition of [email protected]x networks was closely related to the association-dissociation of Zn(II)-iminocarboxyl complexation. Besides, DFT calculations further provided the optimized configuration of metal-ligand complex according to the bond-valence-bond-length correlations." @default.
- W4224884312 created "2022-04-27" @default.
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- W4224884312 date "2022-05-01" @default.
- W4224884312 modified "2023-10-10" @default.
- W4224884312 title "A systematic study on Zn(II)-Iminocarboxyl complexation applied in supramolecular PDMS networks" @default.
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- W4224884312 doi "https://doi.org/10.1016/j.polymer.2022.124896" @default.
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