Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224952148> ?p ?o ?g. }
- W4224952148 abstract "We have used a crossed electron molecular beam setup to investigate the behavior of the anticancer drug temozolomide (TMZ) upon the attachment of low-energy electrons (0–14 eV) in the gas phase. Upon a single electron attachment, eight anionic fragments are observed, the most intense being an anion with mass of 109 u at a resonance energy of 0 eV. Quantum chemical calculations suggest that this ion is generated after the tetrazine ring opens along a N–N bond and its fragments leave the molecule, forming an imidazole-carboxamide species. This ion represents the most abundant fragment, with further fragments following from its dissociation. The tetrazine ring cleavage reaction forming N 2 is thus the driving force of TMZ reactivity upon electron attachment." @default.
- W4224952148 created "2022-04-28" @default.
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- W4224952148 date "2022-04-27" @default.
- W4224952148 modified "2023-10-06" @default.
- W4224952148 title "Dynamics of Ring-Cleavage Reactions in Temozolomide Induced by Low-Energy Electron Attachment" @default.
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- W4224952148 doi "https://doi.org/10.3389/fphy.2022.880689" @default.
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