Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224992057> ?p ?o ?g. }
- W4224992057 endingPage "136621" @default.
- W4224992057 startingPage "136621" @default.
- W4224992057 abstract "A novel tetraphenylporphyrin-C60 supramolecular photocatalyst (SA-TPP-C60) with donor–acceptor (D-A) structure is successfully constructed. Self-assembly of covalently-linked D-A molecule TPP-C60 gives rise to SA-TPP-C60 with highly-ordered layered D-A structure. TPP-C60 molecule is characterized with strong D-A interaction, inducing a significantly larger molecular dipole moment (ca. 4.86 D) than the referential TPP molecule (only 0.04 D). In consequence, robust internal electric field (IEF) with 4.7 times enhancement is built up in SA-TPP-C60, contributing to ultrafast photogenerated charge separation (∼0.5 ps) and enhanced charge transport. Notably, unprecedented long-lived photogenerated charge separation (τ = 26.3 ns) was observed in SA-TPP-C60. Thus, the photocatalytic hydrogen evolution performance of SA-TPP-C60 reached 10.69 mmol g-1h−1, which is about 80 times higher than SA-TPP. Briefly, this study sheds light on D-A structure engineering of supramolecular photocatalysts for high-performance photocatalytic applications." @default.
- W4224992057 created "2022-04-28" @default.
- W4224992057 creator A5004893546 @default.
- W4224992057 creator A5015286714 @default.
- W4224992057 creator A5016508951 @default.
- W4224992057 creator A5020380510 @default.
- W4224992057 creator A5021809579 @default.
- W4224992057 creator A5023634611 @default.
- W4224992057 creator A5024753658 @default.
- W4224992057 creator A5039338730 @default.
- W4224992057 creator A5042919982 @default.
- W4224992057 creator A5047737377 @default.
- W4224992057 creator A5070036224 @default.
- W4224992057 creator A5084455345 @default.
- W4224992057 date "2022-09-01" @default.
- W4224992057 modified "2023-10-13" @default.
- W4224992057 title "Highly efficient photocatalytic hydrogen production via porphyrin-fullerene supramolecular photocatalyst with donor-acceptor structure" @default.
- W4224992057 cites W1832380510 @default.
- W4224992057 cites W1963549289 @default.
- W4224992057 cites W1973836112 @default.
- W4224992057 cites W1976885202 @default.
- W4224992057 cites W2005738001 @default.
- W4224992057 cites W2017331980 @default.
- W4224992057 cites W2038012332 @default.
- W4224992057 cites W2060633595 @default.
- W4224992057 cites W2062852634 @default.
- W4224992057 cites W2087260065 @default.
- W4224992057 cites W2088087732 @default.
- W4224992057 cites W2099466075 @default.
- W4224992057 cites W2111416602 @default.
- W4224992057 cites W2132525235 @default.
- W4224992057 cites W2157788244 @default.
- W4224992057 cites W2200603393 @default.
- W4224992057 cites W2260827383 @default.
- W4224992057 cites W2292726078 @default.
- W4224992057 cites W2311067273 @default.
- W4224992057 cites W2318098234 @default.
- W4224992057 cites W2594464950 @default.
- W4224992057 cites W2600352841 @default.
- W4224992057 cites W2624900231 @default.
- W4224992057 cites W2731435861 @default.
- W4224992057 cites W2754808754 @default.
- W4224992057 cites W2759147296 @default.
- W4224992057 cites W2792341438 @default.
- W4224992057 cites W2794669282 @default.
- W4224992057 cites W2904727927 @default.
- W4224992057 cites W2908404354 @default.
- W4224992057 cites W2921331107 @default.
- W4224992057 cites W2935215275 @default.
- W4224992057 cites W2942287711 @default.
- W4224992057 cites W2942444884 @default.
- W4224992057 cites W2985594156 @default.
- W4224992057 cites W2992967281 @default.
- W4224992057 cites W2996398967 @default.
- W4224992057 cites W2999849639 @default.
- W4224992057 cites W3005126264 @default.
- W4224992057 cites W3008849464 @default.
- W4224992057 cites W3014150554 @default.
- W4224992057 cites W3017490550 @default.
- W4224992057 cites W3033612988 @default.
- W4224992057 cites W3037308739 @default.
- W4224992057 cites W3093638097 @default.
- W4224992057 cites W3096894297 @default.
- W4224992057 cites W3108362766 @default.
- W4224992057 cites W3111219899 @default.
- W4224992057 cites W3120857889 @default.
- W4224992057 cites W3164677796 @default.
- W4224992057 cites W3176506627 @default.
- W4224992057 cites W3195937310 @default.
- W4224992057 cites W4200299682 @default.
- W4224992057 doi "https://doi.org/10.1016/j.cej.2022.136621" @default.
- W4224992057 hasPublicationYear "2022" @default.
- W4224992057 type Work @default.
- W4224992057 citedByCount "13" @default.
- W4224992057 countsByYear W42249920572022 @default.
- W4224992057 countsByYear W42249920572023 @default.
- W4224992057 crossrefType "journal-article" @default.
- W4224992057 hasAuthorship W4224992057A5004893546 @default.
- W4224992057 hasAuthorship W4224992057A5015286714 @default.
- W4224992057 hasAuthorship W4224992057A5016508951 @default.
- W4224992057 hasAuthorship W4224992057A5020380510 @default.
- W4224992057 hasAuthorship W4224992057A5021809579 @default.
- W4224992057 hasAuthorship W4224992057A5023634611 @default.
- W4224992057 hasAuthorship W4224992057A5024753658 @default.
- W4224992057 hasAuthorship W4224992057A5039338730 @default.
- W4224992057 hasAuthorship W4224992057A5042919982 @default.
- W4224992057 hasAuthorship W4224992057A5047737377 @default.
- W4224992057 hasAuthorship W4224992057A5070036224 @default.
- W4224992057 hasAuthorship W4224992057A5084455345 @default.
- W4224992057 hasConcept C112887158 @default.
- W4224992057 hasConcept C121332964 @default.
- W4224992057 hasConcept C161790260 @default.
- W4224992057 hasConcept C162862793 @default.
- W4224992057 hasConcept C178790620 @default.
- W4224992057 hasConcept C185592680 @default.
- W4224992057 hasConcept C192562407 @default.
- W4224992057 hasConcept C202189072 @default.
- W4224992057 hasConcept C26873012 @default.