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- W4224992778 abstract "• A novel fluorescence sensor ( G1 ) was designed and synthesized based on 5-(naphthalen-1-yl)oxazole-4-carbohydrazide and salicylaldehyde. • G1 could be acted as an “off-on-off” sensor to sequentially detect Al 3+ and Cu 2+ with excellent sensitivity and selectivity through different sensing mechanisms. • The optimized structure and energy calculation of G1 , G1 -Al 3+ , and G1 -Cu 2+ were gained by Gaussian09 to demonstrate the binding mechanism. • G1 had been successfully applied for the detection of Al 3+ and Cu 2+ in real water sample with satisfactory recovery and RSD. A novel Schiff base probe N'-(2-hydroxybenzylidene)-5-(naphthalen-1-yl)oxazole-4-carbohydrazide ( G1 ) was designed and prepared based on a condensation of 5-(naphthalen-1-yl)oxazole-4-carbohydrazide with salicylaldehyde. G1 gave out a bright blue luminescence in the introduction of Al 3+ with an ideal selectivity and sensitivity, which could be acted as a fluorescence “turn-on” probe toward Al 3+ . The resulted complex G1- Al 3+ could be applied to be a quenching probe for Cu 2+ . The complex stoichiometry of G1 with Al 3+ and Cu 2+ was confirmed to be 1: 2, via Job's Plot, mass spectrometry titration and theoretical calculation. Moreover, G1 had been successfully applied for monitoring target metal ions in real water sample." @default.
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- W4224992778 date "2022-09-01" @default.
- W4224992778 modified "2023-09-27" @default.
- W4224992778 title "A novel Schiff base sensor through “off-on-off” fluorescence behavior for sequentially monitoring Al3+ and Cu2+" @default.
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- W4224992778 doi "https://doi.org/10.1016/j.jphotochem.2022.113990" @default.
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