FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224993603> ?p ?o ?g. }

• W4224993603 abstract "Abstract Two series of ruthenium complexes with various polypyridyl ligands have been prepared. One series of complexes (5 examples) are featured with tetradentate polypyridyl ligands and two acetonitrile molecules at the axial positions of the coordination sphere; the other series (3 examples) include combinations of a tridentate polypyridyl ligand, one 2,2′‐bipyridine (bpy) or two picolines, and one acetonitrile ligand. All these complexes were fully characterized by their NMR spectra as well as X‐ray single crystal structures. Their electronic absorption and redox data were measured and reported. Of the 8 complexes, three candidates effectively catalyze electrochemical CO 2 reduction reaction (CO 2 RR) in wet acetonitrile medium, generating CO as the major product. All these three catalytically active complexes contain a 2,2′:6′,2′′:6′′,2′′′‐quaterpyridine (qpy) ligand scaffold. A maximum turnover frequency (TOF max ) of>1000 s −1 was achieved for the electrocatalytic CO 2 reduction at a modest overpotential. On the basis of electrochemical and spectroelectrochemical evidences, the CO 2 substrate was proposed to bind with the ruthenium center at the two‐electron reduced state of the complex and then entered the catalytic cycle." @default.
• W4224993603 created "2022-04-28" @default.
• W4224993603 creator A5041355919 @default.
• W4224993603 creator A5049114132 @default.
• W4224993603 creator A5075667866 @default.
• W4224993603 creator A5080933618 @default.
• W4224993603 creator A5082352572 @default.
• W4224993603 date "2022-04-27" @default.
• W4224993603 modified "2023-09-27" @default.
• W4224993603 title "Electrocatalytic CO ₂ Reduction by Molecular Ruthenium Complexes with Polypyridyl Ligands" @default.
• W4224993603 cites W1945139333 @default.
• W4224993603 cites W1966729480 @default.
• W4224993603 cites W1967717080 @default.
• W4224993603 cites W1969298685 @default.
• W4224993603 cites W1978690125 @default.
• W4224993603 cites W1981365516 @default.
• W4224993603 cites W1987897926 @default.
• W4224993603 cites W1988591063 @default.
• W4224993603 cites W1992678038 @default.
• W4224993603 cites W1992864153 @default.
• W4224993603 cites W1993240227 @default.
• W4224993603 cites W1997712324 @default.
• W4224993603 cites W2005821182 @default.
• W4224993603 cites W2008686504 @default.
• W4224993603 cites W2009184234 @default.
• W4224993603 cites W2012782670 @default.
• W4224993603 cites W2022274057 @default.
• W4224993603 cites W2024376521 @default.
• W4224993603 cites W2024382446 @default.
• W4224993603 cites W2028361335 @default.
• W4224993603 cites W2042897851 @default.
• W4224993603 cites W2045374296 @default.
• W4224993603 cites W2049153025 @default.
• W4224993603 cites W2056450153 @default.
• W4224993603 cites W2061694766 @default.
• W4224993603 cites W2062011962 @default.
• W4224993603 cites W2063404506 @default.
• W4224993603 cites W2065268072 @default.
• W4224993603 cites W2075175068 @default.
• W4224993603 cites W2100181695 @default.
• W4224993603 cites W2104596935 @default.
• W4224993603 cites W2118270549 @default.
• W4224993603 cites W2138503485 @default.
• W4224993603 cites W2155245042 @default.
• W4224993603 cites W2213460959 @default.
• W4224993603 cites W2239242857 @default.
• W4224993603 cites W2291518213 @default.
• W4224993603 cites W2315313870 @default.
• W4224993603 cites W2320625878 @default.
• W4224993603 cites W2328726285 @default.
• W4224993603 cites W2332448579 @default.
• W4224993603 cites W2333893976 @default.
• W4224993603 cites W2338384169 @default.
• W4224993603 cites W2414777232 @default.
• W4224993603 cites W2494300389 @default.
• W4224993603 cites W2501478460 @default.
• W4224993603 cites W2552043648 @default.
• W4224993603 cites W2587896894 @default.
• W4224993603 cites W2655505398 @default.
• W4224993603 cites W2742032126 @default.
• W4224993603 cites W2782879485 @default.
• W4224993603 cites W2789921448 @default.
• W4224993603 cites W2803407950 @default.
• W4224993603 cites W2890622349 @default.
• W4224993603 cites W2903365446 @default.
• W4224993603 cites W2936769114 @default.
• W4224993603 cites W2938843478 @default.
• W4224993603 cites W2943781601 @default.
• W4224993603 cites W2954959763 @default.
• W4224993603 cites W2962921416 @default.
• W4224993603 cites W2996797507 @default.
• W4224993603 cites W2997646963 @default.
• W4224993603 cites W2999050709 @default.
• W4224993603 cites W3003167920 @default.
• W4224993603 cites W3004537788 @default.
• W4224993603 cites W3014060633 @default.
• W4224993603 cites W3037300913 @default.
• W4224993603 cites W3134422447 @default.
• W4224993603 cites W4241260143 @default.
• W4224993603 doi "https://doi.org/10.1002/asia.202200217" @default.
• W4224993603 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35384330" @default.
• W4224993603 hasPublicationYear "2022" @default.
• W4224993603 type Work @default.
• W4224993603 citedByCount "2" @default.
• W4224993603 countsByYear W42249936032023 @default.
• W4224993603 crossrefType "journal-article" @default.
• W4224993603 hasAuthorship W4224993603A5041355919 @default.
• W4224993603 hasAuthorship W4224993603A5049114132 @default.
• W4224993603 hasAuthorship W4224993603A5075667866 @default.
• W4224993603 hasAuthorship W4224993603A5080933618 @default.
• W4224993603 hasAuthorship W4224993603A5082352572 @default.
• W4224993603 hasConcept C11111787 @default.
• W4224993603 hasConcept C116569031 @default.
• W4224993603 hasConcept C147789679 @default.
• W4224993603 hasConcept C161790260 @default.
• W4224993603 hasConcept C170493617 @default.
• W4224993603 hasConcept C17525397 @default.
• W4224993603 hasConcept C178790620 @default.
• W4224993603 hasConcept C179104552 @default.
• W4224993603 hasConcept C185592680 @default.

• next