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• W4224995795 endingPage "100494" @default.
• W4224995795 startingPage "100494" @default.
• W4224995795 abstract "Pharmaceutical drug contamination in water nowadays is deteriorating the ecological components. A remedial approach is therefore a necessity. This study focuses on the synthesis of PANI nanofibres employing the oxidative polymerization method using ammonium persulphate (APS) as oxidant. The synthesized nanofibres were characterized using HR-TEM, FT-IR and XRD. The HRTEM image exhibited the nano-range structure of PANI with a rough surface. The FT-IR spectra inferred about the role of surface capping groups involved in the uptake mechanism. The crystallinity of PANI was well assessed by the X-Ray Diffraction analysis. The interaction between the studied drug diclofenac (DC) and polyaniline (PANI) showed a rapid equilibrium time 120 min favored at pH 5.0 achieving maximum adsorptive capacity (qe) of 471.08 mg g −1. The uptake process followed the pseudo-second order kinetic model (R2 = 1) with intra-particle diffusivity model (R2 = 0.9810) as the governing step and best fitting values into Langmuir isotherm model (R2 = 0.9822) inferred about the favourable adsorption of DC forming monolayer over PANI having qm to be 943.83 mg g−1. The drug DC was easily desorbed up to 85.31% by using 0.1 M aq ethanol and was exhausted after five cycles of reusability. The whole adsorptive mechanism involved electrostatic interactions along with hydrogen bonding." @default.
• W4224995795 created "2022-04-28" @default.
• W4224995795 creator A5024627835 @default.
• W4224995795 creator A5072351801 @default.
• W4224995795 date "2022-06-01" @default.
• W4224995795 modified "2023-10-02" @default.
• W4224995795 title "Efficacy of Polyaniline (PANI) nanofibres for capturing Diclofenac (DC) drug from its aqueous solutions" @default.
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• W4224995795 doi "https://doi.org/10.1016/j.jics.2022.100494" @default.
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