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• W4225103616 endingPage "7206" @default.
• W4225103616 startingPage "7201" @default.
• W4225103616 abstract "Here, we report a weakly bound ionic cocrystal, (Et3NCH2Cl)2[ZnCl4], which undergoes a reversible structural phase transition owing to the switched molecular dynamics of the quasi-spherical (Et3NCH2Cl)+ cation from static to dynamic. Interestingly, a unique rolling and moving mechanism is uncovered for such a cation in the high-temperature phase, where its two methylene groups exhibit different kinetic energy barriers. This study provides a meaningful insight into the solid-state molecular dynamics of large-size quasi-spherical molecules that contain both a rigid core and flexible shell." @default.
• W4225103616 created "2022-04-30" @default.
• W4225103616 creator A5004900804 @default.
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• W4225103616 date "2022-04-27" @default.
• W4225103616 modified "2023-10-10" @default.
• W4225103616 title "Insights into the Molecular Dynamics of Quasi-Spherical (Chloromethyl)triethylammonium Confined in a Weakly Bound Ionic Cocrystal" @default.
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• W4225103616 doi "https://doi.org/10.1021/acs.inorgchem.2c00886" @default.
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• W4225103616 hasPublicationYear "2022" @default.
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