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• W4225103639 endingPage "11806" @default.
• W4225103639 startingPage "11796" @default.
• W4225103639 abstract "In this work, vanadium-doped phosphomolybdic acids were evaluated as catalysts in green oxidation routes of terpene alcohols with hydrogen peroxide. A series of phosphomolybdic acids containing a variable load of vanadium cations (i.e., V5+ ions) were synthesized, and tested as catalysts in geraniol oxidation, the model molecule selected. All the catalysts were characterized by powder X-ray diffraction, attenuated diffuse reflectance infrared spectroscopy, UV-Vis spectroscopy, thermogravimetric analysis, N2 adsorption-desorption isotherms, scanning electronic microscopy, X-ray dispersive spectroscopy, and n-butylamine potentiometric titration. Various catalysts were evaluated; phosphomolybdic acids with general formulae H3+n PMo12-n V n O40 (n = 0, 1, 2 and 3), and common Brønsted acids (i.e., H2SO4, H3PO4, and p-toluene sulfonic acid). Among them, vanadium monosubstituted phosphomolybdic acid was the most active catalyst and selective toward epoxide. The effect of main reaction variables, such as temperature, load catalyst, and reactant stoichiometry was assessed. Evaluating the effect of substrate, it was verified that only allylic alcohols such as geraniol and nerol were successfully epoxidized, demonstrating that this is a hydroxy group-assisted reaction. The effect of vanadium doping on the physicochemical properties of the phosphomolybdic acid catalysts was evaluated and used to explain their catalytic performance." @default.
• W4225103639 created "2022-04-30" @default.
• W4225103639 creator A5015020825 @default.
• W4225103639 creator A5044861401 @default.
• W4225103639 creator A5085947073 @default.
• W4225103639 date "2022-01-01" @default.
• W4225103639 modified "2023-09-26" @default.
• W4225103639 title "Vanadium-doped phosphomolybdic acids as catalysts for geraniol oxidation with hydrogen peroxide" @default.
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• W4225103639 doi "https://doi.org/10.1039/d2ra01258h" @default.
• W4225103639 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35481091" @default.
• W4225103639 hasPublicationYear "2022" @default.
• W4225103639 type Work @default.
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