FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4225147757> ?p ?o ?g. }

• W4225147757 endingPage "053036" @default.
• W4225147757 startingPage "053036" @default.
• W4225147757 abstract "Abstract The dispute about whether the 1 s core-hole is localized on one atom or delocalized over both in a homonuclear diatomic molecule has continued for decades, which has been extensively studied by the photoelectron and electron–ion coincidence spectroscopies. For N 2 , if the 1 s core-hole is delocalized, the K-shell excitation into the 1 π g orbital should split into two components, i.e., the dipole-allowed transition from the ungerade 1 σ u state and the dipole-forbidden transition from the gerade 1 σ g state. However, only the dipole-allowed transition has been observed up to now. Here, we report the inner-shell electron energy loss spectra of N 2 at different scattering angles with an incident electron energy of 1500 eV and an energy resolution of 65 meV. The vibrational structures of both the dipole-allowed <?CDATA ${(1s{sigma }_{u})}^{-1}{(1{pi }_{g})}^{1}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline overflow=scroll> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:mi>s</mml:mi> <mml:msub> <mml:mrow> <mml:mi>σ</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>u</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>π</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> and dipole-forbidden <?CDATA ${(1s{sigma }_{g})}^{-1}{(1{pi }_{g})}^{1}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline overflow=scroll> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:mi>s</mml:mi> <mml:msub> <mml:mrow> <mml:mi>σ</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>π</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> states of N 2 have been identified at different momentum transfers. The splitting between the <?CDATA ${(1{sigma }_{g})}^{-1}{(1{pi }_{g})}^{1}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline overflow=scroll> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>σ</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>π</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> and <?CDATA ${(1{sigma }_{u})}^{-1}{(1{pi }_{g})}^{1}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline overflow=scroll> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>σ</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>u</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mo>−</mml:mo> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> <mml:msup> <mml:mrow> <mml:mrow> <mml:mo stretchy=false>(</mml:mo> <mml:mrow> <mml:mn>1</mml:mn> <mml:msub> <mml:mrow> <mml:mi>π</mml:mi> </mml:mrow> <mml:mrow> <mml:mi>g</mml:mi> </mml:mrow> </mml:msub> </mml:mrow> <mml:mo stretchy=false>)</mml:mo> </mml:mrow> </mml:mrow> <mml:mrow> <mml:mn>1</mml:mn> </mml:mrow> </mml:msup> </mml:math> states with the reverse symmetry is determined to be 67 ± 7 meV. Moreover, the momentum transfer dependence behavior of the transition intensity ratio agrees with the theoretical predictions, as increasing to a maximum and then decreasing. The experimental observations clearly show that the inner most electrons can be described by 1 σ g and 1 σ u , which indicates that the inner-shell 1 s core-hole of N 2 is delocalized over two N atoms based on the excitation process." @default.
• W4225147757 created "2022-05-01" @default.
• W4225147757 creator A5035418730 @default.
• W4225147757 creator A5035554383 @default.
• W4225147757 creator A5054744458 @default.
• W4225147757 creator A5067303826 @default.
• W4225147757 creator A5070489126 @default.
• W4225147757 date "2022-05-01" @default.
• W4225147757 modified "2023-09-26" @default.
• W4225147757 title "Probing the delocalized core-hole via inner-shell excitation in N₂" @default.
• W4225147757 cites W1658090611 @default.
• W4225147757 cites W1964840454 @default.
• W4225147757 cites W1975284679 @default.
• W4225147757 cites W1985445350 @default.
• W4225147757 cites W1985523090 @default.
• W4225147757 cites W2001796236 @default.
• W4225147757 cites W2003462273 @default.
• W4225147757 cites W2004136854 @default.
• W4225147757 cites W2009208715 @default.
• W4225147757 cites W2009322333 @default.
• W4225147757 cites W2021232630 @default.
• W4225147757 cites W2023613662 @default.
• W4225147757 cites W2028806420 @default.
• W4225147757 cites W2028980044 @default.
• W4225147757 cites W2047587199 @default.
• W4225147757 cites W2048892102 @default.
• W4225147757 cites W2051220170 @default.
• W4225147757 cites W2057327355 @default.
• W4225147757 cites W2061089687 @default.
• W4225147757 cites W2062048338 @default.
• W4225147757 cites W2062360768 @default.
• W4225147757 cites W2065861873 @default.
• W4225147757 cites W2070304978 @default.
• W4225147757 cites W2071445138 @default.
• W4225147757 cites W2086794306 @default.
• W4225147757 cites W2089315164 @default.
• W4225147757 cites W2090070417 @default.
• W4225147757 cites W2092441474 @default.
• W4225147757 cites W2095393513 @default.
• W4225147757 cites W2210259022 @default.
• W4225147757 cites W2325714598 @default.
• W4225147757 cites W2335002023 @default.
• W4225147757 cites W2576320076 @default.
• W4225147757 cites W2590715552 @default.
• W4225147757 cites W2980985751 @default.
• W4225147757 cites W3005889336 @default.
• W4225147757 cites W3116086627 @default.
• W4225147757 cites W4240764850 @default.
• W4225147757 doi "https://doi.org/10.1088/1367-2630/ac6bb7" @default.
• W4225147757 hasPublicationYear "2022" @default.
• W4225147757 type Work @default.
• W4225147757 citedByCount "1" @default.
• W4225147757 countsByYear W42251477572022 @default.
• W4225147757 crossrefType "journal-article" @default.
• W4225147757 hasAuthorship W4225147757A5035418730 @default.
• W4225147757 hasAuthorship W4225147757A5035554383 @default.
• W4225147757 hasAuthorship W4225147757A5054744458 @default.
• W4225147757 hasAuthorship W4225147757A5067303826 @default.
• W4225147757 hasAuthorship W4225147757A5070489126 @default.
• W4225147757 hasBestOaLocation W42251477571 @default.
• W4225147757 hasConcept C121332964 @default.
• W4225147757 hasConcept C184779094 @default.
• W4225147757 hasConcept C62520636 @default.
• W4225147757 hasConcept C70050531 @default.
• W4225147757 hasConcept C72782756 @default.
• W4225147757 hasConcept C8058405 @default.
• W4225147757 hasConceptScore W4225147757C121332964 @default.
• W4225147757 hasConceptScore W4225147757C184779094 @default.
• W4225147757 hasConceptScore W4225147757C62520636 @default.
• W4225147757 hasConceptScore W4225147757C70050531 @default.
• W4225147757 hasConceptScore W4225147757C72782756 @default.
• W4225147757 hasConceptScore W4225147757C8058405 @default.
• W4225147757 hasFunder F4320321001 @default.
• W4225147757 hasIssue "5" @default.
• W4225147757 hasLocation W42251477571 @default.
• W4225147757 hasOpenAccess W4225147757 @default.
• W4225147757 hasPrimaryLocation W42251477571 @default.
• W4225147757 hasRelatedWork W1978505944 @default.
• W4225147757 hasRelatedWork W1997086491 @default.
• W4225147757 hasRelatedWork W2001933581 @default.
• W4225147757 hasRelatedWork W2041280169 @default.
• W4225147757 hasRelatedWork W2048498597 @default.
• W4225147757 hasRelatedWork W2060653029 @default.
• W4225147757 hasRelatedWork W2070062755 @default.
• W4225147757 hasRelatedWork W2074248911 @default.
• W4225147757 hasRelatedWork W2946468617 @default.
• W4225147757 hasRelatedWork W3082172574 @default.
• W4225147757 hasVolume "24" @default.
• W4225147757 isParatext "false" @default.
• W4225147757 isRetracted "false" @default.
• W4225147757 workType "article" @default.