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- W4225159470 abstract "Abstract Herein, the design and synthesis of a highly photoluminescent and electrically conductive metal–organic framework [Zn{Cu‐ p ‐H 6 TPPA}]⋅2 [(CH 3 ) 2 NH] (designated as GTUB3), which is constructed using the 5,10,15,20‐tetrakis [ p ‐phenylphosphonic acid] porphyrin ( p ‐H 8 TPPA) organic linker, is reported. The bandgap of GTUB3 is measured to be 1.45 and 1.48 eV using diffuse reflectance spectroscopy and photoluminescence (PL) spectroscopy, respectively. The PL decay measurement yields a charge carrier lifetime of 40.6 ns. Impedance and DC measurements yield average electrical conductivities of 0.03 and 4 S m −1 , respectively, making GTUB3 a rare example of an electrically conductive 3D metal–organic framework. Thermogravimetric analysis reveals that the organic components of GTUB3 are stable up to 400 °C. Finally, its specific surface area and pore volume are calculated to be 622 m 2 g −1 and 0.43 cm 3 g −1 , respectively, using grand canonical Monte Carlo. Owing to its porosity and high electrical conductivity, GTUB3 may be used as a low‐cost electrode material in next generation of supercapacitors, while its low bandgap and high photoluminescence make it a promising material for optoelectronic applications." @default.
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- W4225159470 date "2022-04-30" @default.
- W4225159470 modified "2023-10-10" @default.
- W4225159470 title "Electrically Conductive Photoluminescent Porphyrin Phosphonate Metal–Organic Frameworks" @default.
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- W4225159470 doi "https://doi.org/10.1002/adom.202200213" @default.
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