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- W4225166189 abstract "The catalytic asymmetric synthesis of chiral compounds with multiple stereogenic elements via a single catalytic process is challenging. This paper proposes a domino asymmetric electrophilic halocyclization strategy for constructing heterocycloalkenyl atropisomeric spiroketal lactones. A single catalyst was utilized to realize two independent stereodetermining steps. Various spiroketal lactones containing both chiral axes and chiral centers were prepared in excellent yields with excellent enantioselectivity and diastereoselective (up to 99% ee and >20:1 dr)." @default.
- W4225166189 created "2022-05-01" @default.
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- W4225166189 date "2022-04-05" @default.
- W4225166189 modified "2023-10-16" @default.
- W4225166189 title "Organocatalytic Enantioselective Construction of Spiroketal Lactones Bearing Axial and Central Chirality via an Asymmetric Domino Reaction" @default.
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- W4225166189 doi "https://doi.org/10.1021/acs.orglett.2c00845" @default.
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