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- W4225293821 abstract "The development of efficient sensors for detecting water content in organic solvents is highly desirable for various cases in the chemical industry. Relevant sensors based on luminescent materials are promising due to their superior sensitivity and visualization. However, reported luminescent probes are either aggregation-caused quenching-type molecules, which present an emission quenching effect in high water content, or aggregation induced emission-type luminogens, which exhibit weak emission in organic solvents. This factor narrows the targeted water-content sensing range. Herein, we developed a series of indoline-based donor-acceptor-donor luminogens involving twist intramolecular charge transfer and an aggregation-induced emission effect, which exhibited a unique on-off-on emission behavior in tetrahydrofuran with the continuous increase of water content from 0% to 99%. Simultaneously, the emission wavelength underwent a process of first red-shift and then blue-shift. Three-dimensional working curves based upon the log value of wavelength and emission intensity ratio versus water content in tetrahydrofuran were established with two-stage characteristics, aiming to visually detect a wide range of water content in organic solvents. Such a sensing method offers extra sensitivity, convenience, and accuracy." @default.
- W4225293821 created "2022-05-05" @default.
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- W4225293821 date "2022-05-02" @default.
- W4225293821 modified "2023-09-26" @default.
- W4225293821 title "Two-Stage Three-Dimensional Luminescent Sensing Strategy for Precisely Detecting a Wide Range of Water Content in Tetrahydrofuran" @default.
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- W4225293821 doi "https://doi.org/10.1021/acs.analchem.1c05600" @default.
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