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- W4225371127 endingPage "109529" @default.
- W4225371127 startingPage "109529" @default.
- W4225371127 abstract "An iodine-functionalized metal–organic framework (MOF), UiO-68-I, was synthesized. UiO-68-I showed good catalytic activity for dibromination of alkenes and alkynes with a low catalyst loading of 1% and was able to be recycled and recovered efficiently. Mechanistic studies suggest that UiO-68-I may trigger the formation of molecular bromine through a radical intermediate and thus accelerate the reaction. The activity and stability of UiO-68-I outperforms most earlier reports on organoiodine catalysts, showing the great potential of iodine-functionalized MOFs as recyclable heterogeneous hypervalent iodine reagents or catalysts." @default.
- W4225371127 created "2022-05-05" @default.
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- W4225371127 date "2022-07-01" @default.
- W4225371127 modified "2023-09-23" @default.
- W4225371127 title "An Iodine-Functionalized Metal–Organic framework for catalytic alkene bromination" @default.
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- W4225371127 doi "https://doi.org/10.1016/j.inoche.2022.109529" @default.
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