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- W4225420347 abstract "• Solution-processed aluminum titanium oxide(ATO) as a gate insulator is investigated. • HCl was used as hydrolysis catalyst. • ATO films had improved dielectric properties at reduced annealing temperature. • The best ATO film resulted in excellent electrical properties of transistor. This study investigated the effect of hydrochloric acid (HCl) addition on the dielectric properties of solution-processed aluminum titanium oxide (ATO) applied to thin-film transistors (TFTs) as a gate insulator layer. The formation of the solution-processed ATO film can be accelerated by adding HCl to the precursor solution because of the hydrolysis catalyst effect of HCl. The solution-processed ATO film exhibits higher crystallinity as the amount of HCl added increases. Furthermore, the addition of HCl suppresses the formation of oxygen vacancies, which can act as defect states in the ATO film. Consequently, the optimized ATO film annealed at 450 ℃ exhibited minimum leakage current density level of 5.14×10 −9 A/cm 2 at 0.33 MV/cm and dielectric constant of 13.9 when HCl of 2 ml was added to the precursor solution. These results are comparable with the dielectric properties of the ATO film annealed at 750 ℃ without HCl addition, because HCl addition catalyses hydrolysis and enhances the formation of metal-oxide bonding. Solution-processed amorphous indium-gallium-zinc oxide (IGZO) TFTs using the optimized ATO/AlO x film as gate insulator displayed excellent electrical properties such as threshold voltage of 0.17 V, field-effect mobility of 2.59 cm 2 /V∙s, subthreshold swing of 0.22 V/dec, and on/off ratio of 4.54×10 5 . In addition, the IGZO TFT with the ATO gate insulator exhibited superior current driving capability compared to that of silicon dioxide (SiO 2 ). These results indicate that solution-processed ATO films with HCl addition could be promising candidates for gate insulator layers in achieving low power consumption, high performance, and low cost TFTs." @default.
- W4225420347 created "2022-05-05" @default.
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- W4225420347 date "2022-07-01" @default.
- W4225420347 modified "2023-10-17" @default.
- W4225420347 title "Effect of hydrochloric acid addition on dielectric properties of solution-processed aluminum titanium oxide thin film annealed at low temperature" @default.
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- W4225420347 doi "https://doi.org/10.1016/j.tsf.2022.139277" @default.
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