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- W4225432544 abstract "Abstract The radical Friedländer hetero-annulation of 2-aminoaryl ketone and -methylene carbonyl compound was used to develop a green tandem approach for the metal-free synthesis of polysubstitutedquinolines. At room temperature in an ethanol solvent, photo-excited state functions generated from MB + were used as single-electron transfer (SET) and energy transfer (EnT) catalysts, utilizing visible light as a renewable energy source in the air atmosphere. The purpose of this research is to increase the use of a nonmetal cationic dye that is both inexpensive and widely available. High yields, energy-effectiveness, high atom economy, time-saving features of the reaction, and operational simplicity, and the least amount of a catalyst are the benefits of this study. As a result, a wide range of ecological and long-term chemical properties are obtained. Polysubstitutedquinolines' turnover number (TON) and turnover frequency (TOF) have been calculated. Surprisingly, such cyclization can be accomplished on a gram scale, indicating that the process has industrial potential." @default.
- W4225432544 created "2022-05-05" @default.
- W4225432544 creator A5063712822 @default.
- W4225432544 date "2022-05-04" @default.
- W4225432544 modified "2023-10-14" @default.
- W4225432544 title "The development of Friedländer heteroannulation through a single electron transfer and energy transfer pathway using methylene blue (MB+)" @default.
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- W4225432544 doi "https://doi.org/10.1038/s41598-022-11349-8" @default.
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