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- W4225665820 abstract "Integrating different types of supramolecular interactions opens the possibility to generate nanoparticle surfactants (NPSs) at the liquid-liquid interface that are responsive to multiple stimuli. Here we develop a covalently modified polyoxometalate/β-cyclodextrin (POM/β-CD) organic-inorganic hybrid, consisting of a negatively charged POM cluster with β-CD host groups. The POM/β-CD hybrid can be dispersed in water and interacts at a water/oil interface with ligands dissolved in an oil phase through electrostatic or host-guest interactions, thereby generating POM-surfactants (POMSs) having pH, redox, and guest-competitive responsiveness, respectively. By taking advantage of the jamming of POMSs at the interface, a reconfigurable all-liquid system could be produced that is responsive to orthogonal changes in the external environment." @default.
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- W4225665820 date "2022-04-21" @default.
- W4225665820 modified "2023-10-14" @default.
- W4225665820 title "Polyoxometalate‐Surfactant Assemblies: Responsiveness to Orthogonal Stimuli" @default.
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- W4225665820 doi "https://doi.org/10.1002/anie.202203741" @default.
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