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• W4225854037 abstract "Multi-reference configuration interaction (MRCI) approach with Davison size-extensivity correction (+Q) is employed to calculate the potential curves and dipole moments of <inline-formula><tex-math id=Z-20220715092522>begin{document}${X^1}Sigma _{rm{g}}^ + ,{a^prime }^1Sigma _{rm{u}}^ - ,{a^1}{Pi _{rm{g}}}$end{document}</tex-math><alternatives><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715092522.jpg/><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715092522.png/></alternatives></inline-formula> and <inline-formula><tex-math id=Z-20220715092543>begin{document}$b{}^1{Pi _{rm u}}$end{document}</tex-math><alternatives><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715092543.jpg/><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715092543.png/></alternatives></inline-formula> electronic states of N₂. The spectroscopic constants and vibrational level spaceings are calculated and in excellent agreement with the available theoretical results and experimental data. Based on the calculated molecular structure parameters, the opacities of N₂ in a temperature range of 295–20000 K under a pressure of 100 atm (1 atm = 1.01×10⁵ Pa) are presented. The results demonstrate that the wavelength range of absorption cross sections are enlarged with the temperature increasing. Moreover, the cross sections are mainly dominated in the range of ultraviolet for the cases with temperature <i>T</i> < 5000 K, while the obvious population can be found in the infrared ranges for the cases with temperature <i>T</i> > 10000 K due to the contribution of the excited states. The influence of temperature on the opacities of nitrogen molecule are investigated in the present work, which can provide theoretical and data support for researches of astrophysics and nuclear weapons." @default.
• W4225854037 created "2022-05-05" @default.
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• W4225854037 date "2022-01-01" @default.
• W4225854037 modified "2023-09-26" @default.
• W4225854037 title "Opacities of <inline-formula><tex-math id=Z-20220715033133-1>begin{document}${ X}^1Sigma^+_{rm g}, a'{}^1Sigma^-_{rm u}, a{}^1Pi_{rm g} text{ and } { b}^1Pi_{rm u}$end{document}</tex-math><alternatives><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715033133-1.jpg/><graphic xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=14-20220043_Z-20220715033133-1.png/></alternatives></inline-formula> …" @default.
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• W4225854037 doi "https://doi.org/10.7498/aps.71.20220043" @default.
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