Matches in SemOpenAlex for { <https://semopenalex.org/work/W4226021184> ?p ?o ?g. }
- W4226021184 endingPage "15968" @default.
- W4226021184 startingPage "15960" @default.
- W4226021184 abstract "Stable and catalytically active nano particles with small sizes are of paramount importance in catalysis, but the preparation of such particles has been a great challenge due to their propensity to aggregate into large and less active particles. Herein, we would like to report the formation of ultra-small and uncommon RhO2 particles within an organic cage in the homogeneous solution, and the soluble assembly showed both better durability and high activity towards ammonia borane methanolysis to generate hydrogen gas. A volcanic plot of the turnover frequencies (TOFs) over the molar amount of Rh per cage was demonstrated, and RhO2[email protected] showed a TOF of around 286 min−1 at room temperature. Our assembly also showed better durability during the catalysis in contrast to NPs made from pure rhodium acetate, and there was no aggregation formed after five runs. We further demonstrated the Michaelis-Menten model through the kinetic study, an indication that the catalytic reaction happened within the organic cage. The actual active sites of the catalyst was zero-valent metal Rh. Interestingly the installation of azobenzene groups at the opening of the cage led to gated activity through the trans-cis conformation interchange, due to the different steric hindrances affecting the diffusion rates of reactants." @default.
- W4226021184 created "2022-05-05" @default.
- W4226021184 creator A5021461635 @default.
- W4226021184 creator A5039427501 @default.
- W4226021184 creator A5052421234 @default.
- W4226021184 creator A5058713341 @default.
- W4226021184 creator A5069881644 @default.
- W4226021184 creator A5090597935 @default.
- W4226021184 date "2022-04-01" @default.
- W4226021184 modified "2023-09-27" @default.
- W4226021184 title "Rhodium(0) nano particles within an organic cage with better durability and gated activity for hydrogen generation reaction" @default.
- W4226021184 cites W1165440086 @default.
- W4226021184 cites W1469126758 @default.
- W4226021184 cites W1965530799 @default.
- W4226021184 cites W1969883898 @default.
- W4226021184 cites W1982931420 @default.
- W4226021184 cites W1984584895 @default.
- W4226021184 cites W2007121911 @default.
- W4226021184 cites W2012930483 @default.
- W4226021184 cites W2013200143 @default.
- W4226021184 cites W2019174273 @default.
- W4226021184 cites W2021487595 @default.
- W4226021184 cites W2021602221 @default.
- W4226021184 cites W2032617158 @default.
- W4226021184 cites W2042670016 @default.
- W4226021184 cites W2047700263 @default.
- W4226021184 cites W2061904132 @default.
- W4226021184 cites W2068339282 @default.
- W4226021184 cites W2084953325 @default.
- W4226021184 cites W2094703768 @default.
- W4226021184 cites W2095853776 @default.
- W4226021184 cites W2098297064 @default.
- W4226021184 cites W2104755463 @default.
- W4226021184 cites W2124413194 @default.
- W4226021184 cites W2129011294 @default.
- W4226021184 cites W2136094441 @default.
- W4226021184 cites W2171636864 @default.
- W4226021184 cites W2207647994 @default.
- W4226021184 cites W2313151506 @default.
- W4226021184 cites W2331255865 @default.
- W4226021184 cites W2426795413 @default.
- W4226021184 cites W2507423338 @default.
- W4226021184 cites W2511420986 @default.
- W4226021184 cites W2560209319 @default.
- W4226021184 cites W2711977086 @default.
- W4226021184 cites W2739765632 @default.
- W4226021184 cites W2782381422 @default.
- W4226021184 cites W2788232474 @default.
- W4226021184 cites W2789593697 @default.
- W4226021184 cites W2792589001 @default.
- W4226021184 cites W2809829266 @default.
- W4226021184 cites W2821435386 @default.
- W4226021184 cites W2899232133 @default.
- W4226021184 cites W2903817271 @default.
- W4226021184 cites W2914948637 @default.
- W4226021184 cites W2915476770 @default.
- W4226021184 cites W2922871677 @default.
- W4226021184 cites W2942915186 @default.
- W4226021184 cites W2944454105 @default.
- W4226021184 cites W2952367286 @default.
- W4226021184 cites W2965851739 @default.
- W4226021184 cites W3004756150 @default.
- W4226021184 cites W3017180782 @default.
- W4226021184 cites W3022114877 @default.
- W4226021184 cites W3024419935 @default.
- W4226021184 cites W3045911856 @default.
- W4226021184 cites W3084327784 @default.
- W4226021184 cites W3094024045 @default.
- W4226021184 cites W3120729387 @default.
- W4226021184 cites W3215245607 @default.
- W4226021184 cites W4231251373 @default.
- W4226021184 cites W4244790296 @default.
- W4226021184 cites W4250686082 @default.
- W4226021184 doi "https://doi.org/10.1016/j.ijhydene.2022.03.086" @default.
- W4226021184 hasPublicationYear "2022" @default.
- W4226021184 type Work @default.
- W4226021184 citedByCount "3" @default.
- W4226021184 countsByYear W42260211842023 @default.
- W4226021184 crossrefType "journal-article" @default.
- W4226021184 hasAuthorship W4226021184A5021461635 @default.
- W4226021184 hasAuthorship W4226021184A5039427501 @default.
- W4226021184 hasAuthorship W4226021184A5052421234 @default.
- W4226021184 hasAuthorship W4226021184A5058713341 @default.
- W4226021184 hasAuthorship W4226021184A5069881644 @default.
- W4226021184 hasAuthorship W4226021184A5090597935 @default.
- W4226021184 hasConcept C104304963 @default.
- W4226021184 hasConcept C112887158 @default.
- W4226021184 hasConcept C127413603 @default.
- W4226021184 hasConcept C155672457 @default.
- W4226021184 hasConcept C159985019 @default.
- W4226021184 hasConcept C161790260 @default.
- W4226021184 hasConcept C171250308 @default.
- W4226021184 hasConcept C178790620 @default.
- W4226021184 hasConcept C185592680 @default.
- W4226021184 hasConcept C192562407 @default.
- W4226021184 hasConcept C202189072 @default.
- W4226021184 hasConcept C2778470625 @default.
- W4226021184 hasConcept C32909587 @default.