Matches in SemOpenAlex for { <https://semopenalex.org/work/W4226280212> ?p ?o ?g. }
- W4226280212 abstract "Abstract Hierarchical organization of self‐assembled structures into superstructures is omnipresent in Nature but has been rarely achieved in synthetic molecular assembly due to the absence of clear structural rules. We herein report on the self‐assembly of scissor‐shaped azobenzene dyads which form discrete nanotoroids that further organize into 2D porous networks. The steric demand of the peripheral aliphatic units diminishes the trend of the azobenzene dyad to constitute stackable nanotoroids in solution, thus affording isolated (unstackable) nanotoroids upon cooling. Upon drying, these nanotoroids organize at graphite surface to form well‐defined 2D porous networks. The photoirradiation with UV and visible light enabled reversible dissociation and reconstruction of nanotoroids through the efficient trans↔cis isomerization of azobenzene moieties in solution." @default.
- W4226280212 created "2022-05-05" @default.
- W4226280212 creator A5001143892 @default.
- W4226280212 creator A5018368779 @default.
- W4226280212 creator A5030716988 @default.
- W4226280212 creator A5037300503 @default.
- W4226280212 creator A5037989942 @default.
- W4226280212 creator A5043350589 @default.
- W4226280212 creator A5063724126 @default.
- W4226280212 creator A5087603309 @default.
- W4226280212 date "2021-12-15" @default.
- W4226280212 modified "2023-10-15" @default.
- W4226280212 title "Biasing the Hierarchy Motifs of Nanotoroids: from 1D Nanotubes to 2D Porous Networks" @default.
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