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• W4226321608 abstract "A metallic covalently bonded carbon allotrope is predicted via first principles calculations. It is composed of an $sp^3$ carbon framework that acts as a diamond anvil cell by constraining the distance between parallel cis-polyacetylene chains. The distance between these $sp^2$ carbon atoms renders the phase metallic, and yields two well-nested nearly parallel bands that span the Fermi level. Calculations show that this phase is a conventional superconductor, with the motions of the $sp^2$ carbons being key contributors to the electron phonon coupling. The $sp^3$ carbon atoms impart superior mechanical properties, with a predicted Vickers hardness of 48~GPa. This phase, metastable at ambient conditions, could be made via cold compression of graphite to 40~GPa. A family of multifunctional materials with tunable superconducting and mechanical properties could be derived from this phase by varying the $sp^2$ versus $sp^3$ carbon content and by doping." @default.
• W4226321608 created "2022-05-05" @default.
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• W4226321608 date "2022-06-24" @default.
• W4226321608 modified "2023-10-01" @default.
• W4226321608 title "The Microscopic Diamond Anvil Cell: Stabilization of Superhard, Superconducting Carbon Allotropes at Ambient Pressure" @default.
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• W4226321608 doi "https://doi.org/10.1002/anie.202205129" @default.
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