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- W4226323912 abstract "Abstract Previous methods on Co III ‐catalyzed asymmetric C−H activation rely on the use of tailor‐made cyclopentadienyl‐ligated Co III complexes, which require lengthy steps for the preparation. Herein, we report an unprecedented enantioselective C−H functionalization enabled by a simple cobalt/salicyloxazoline (Salox) catalysis. The chiral Salox ligands can be easily prepared in one step from salicylonitrile and chiral amino alcohols. A broad range of P‐stereogenic compounds were synthesized in high yields with excellent enantioselectivities (45 examples, up to 99 % yield and >99 % ee). The isolation and characterization of several intermediates provided insights into the generation of active catalytic cobalt species, the action of Salox, and the mode of stereocontrol." @default.
- W4226323912 created "2022-05-05" @default.
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- W4226323912 date "2022-04-21" @default.
- W4226323912 modified "2023-09-28" @default.
- W4226323912 title "Cobalt/Salox‐Catalyzed Enantioselective C−H Functionalization of Arylphosphinamides" @default.
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- W4226323912 doi "https://doi.org/10.1002/ange.202202892" @default.
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