Matches in SemOpenAlex for { <https://semopenalex.org/work/W4226400568> ?p ?o ?g. }
- W4226400568 endingPage "821" @default.
- W4226400568 startingPage "814" @default.
- W4226400568 abstract "Abstract Synthetic reaction of a Cu(II) complex containing aniline moiety (Cu( atpa )) ( atpa = N ‐(anthracen‐9‐ylmethyl)‐2‐((bis(pyridin‐2‐ylmethyl)amino) with an excess Cu(ClO 4 ) 2 in CH 3 CN produced an unusual species, which was not corresponding to the original ligand atpa , Cu(ClO 4 ) 2 nor [Cu( atpa )] 2+ . It was proposed that the new species was generated via electron transfer between aniline‐containing N‐based ligand and Cu(ClO 4 ) 2 , resulting in oxidative ligand cleavage. Monitoring the reaction of Cu( atpa ) with Cu(ClO 4 ) 2 for a period of time revealed a gradual decrease of an active species, concomitant with the growth of a variety of organic fractions including 9‐anthraldehyde and anthraquinone compounds. Cu( tpa ) (Cu coordinated with tripodal amine ligand without anthracene analogue) was also detected from this reaction. This finding was indicative of an oxidative ligand cleavage via the N ‐dealkylation pathway. In addition to oxidative ligand cleavage, the new species was competent to oxidize other substrates such as triphenylphosphine (PPh 3 ) as well." @default.
- W4226400568 created "2022-05-05" @default.
- W4226400568 creator A5042485468 @default.
- W4226400568 creator A5050002740 @default.
- W4226400568 creator A5085967185 @default.
- W4226400568 date "2022-04-06" @default.
- W4226400568 modified "2023-09-27" @default.
- W4226400568 title "Oxidative ligand cleavage in a copper( <scp>II</scp> ) complex containing aniline moiety induced by copper( <scp>II</scp> ) perchlorate in acetonitrile" @default.
- W4226400568 cites W1811391225 @default.
- W4226400568 cites W1932880900 @default.
- W4226400568 cites W1967957905 @default.
- W4226400568 cites W1969362148 @default.
- W4226400568 cites W1971831162 @default.
- W4226400568 cites W1972118010 @default.
- W4226400568 cites W1975507615 @default.
- W4226400568 cites W1977708744 @default.
- W4226400568 cites W1979103178 @default.
- W4226400568 cites W1979646736 @default.
- W4226400568 cites W1979723373 @default.
- W4226400568 cites W1979889714 @default.
- W4226400568 cites W1982558875 @default.
- W4226400568 cites W1984820245 @default.
- W4226400568 cites W1996941025 @default.
- W4226400568 cites W1999761740 @default.
- W4226400568 cites W2006277851 @default.
- W4226400568 cites W2019768314 @default.
- W4226400568 cites W2020375171 @default.
- W4226400568 cites W2023275711 @default.
- W4226400568 cites W2023487779 @default.
- W4226400568 cites W2024584544 @default.
- W4226400568 cites W2025610802 @default.
- W4226400568 cites W2035111929 @default.
- W4226400568 cites W2038130420 @default.
- W4226400568 cites W2038206627 @default.
- W4226400568 cites W2038896761 @default.
- W4226400568 cites W2039771131 @default.
- W4226400568 cites W2042539224 @default.
- W4226400568 cites W2047762078 @default.
- W4226400568 cites W2050379798 @default.
- W4226400568 cites W2052272072 @default.
- W4226400568 cites W2053577856 @default.
- W4226400568 cites W2054475350 @default.
- W4226400568 cites W2059756708 @default.
- W4226400568 cites W2059873861 @default.
- W4226400568 cites W2062651906 @default.
- W4226400568 cites W2065497508 @default.
- W4226400568 cites W2069874612 @default.
- W4226400568 cites W2072336629 @default.
- W4226400568 cites W2078329357 @default.
- W4226400568 cites W2079487076 @default.
- W4226400568 cites W2081298460 @default.
- W4226400568 cites W2086799981 @default.
- W4226400568 cites W2088003592 @default.
- W4226400568 cites W2088150999 @default.
- W4226400568 cites W2090187595 @default.
- W4226400568 cites W2092744078 @default.
- W4226400568 cites W2093585657 @default.
- W4226400568 cites W2095295924 @default.
- W4226400568 cites W2116582201 @default.
- W4226400568 cites W2119913861 @default.
- W4226400568 cites W2135929021 @default.
- W4226400568 cites W2156732153 @default.
- W4226400568 cites W2159252513 @default.
- W4226400568 cites W2161605408 @default.
- W4226400568 cites W2165179223 @default.
- W4226400568 cites W2170170379 @default.
- W4226400568 cites W2205643310 @default.
- W4226400568 cites W2310577840 @default.
- W4226400568 cites W2318715202 @default.
- W4226400568 cites W2320425792 @default.
- W4226400568 cites W2326475605 @default.
- W4226400568 cites W2330645125 @default.
- W4226400568 cites W2503358467 @default.
- W4226400568 cites W2504256884 @default.
- W4226400568 cites W2624910054 @default.
- W4226400568 cites W2752435793 @default.
- W4226400568 cites W2783630370 @default.
- W4226400568 cites W2892280305 @default.
- W4226400568 cites W2897805778 @default.
- W4226400568 cites W2904086328 @default.
- W4226400568 cites W2917427606 @default.
- W4226400568 cites W2950770179 @default.
- W4226400568 cites W2951019347 @default.
- W4226400568 cites W2951947128 @default.
- W4226400568 cites W2953316264 @default.
- W4226400568 cites W3004746832 @default.
- W4226400568 cites W3048771470 @default.
- W4226400568 cites W3113283117 @default.
- W4226400568 cites W4239280048 @default.
- W4226400568 cites W760762798 @default.
- W4226400568 doi "https://doi.org/10.1002/bkcs.12522" @default.
- W4226400568 hasPublicationYear "2022" @default.
- W4226400568 type Work @default.
- W4226400568 citedByCount "0" @default.
- W4226400568 crossrefType "journal-article" @default.
- W4226400568 hasAuthorship W4226400568A5042485468 @default.
- W4226400568 hasAuthorship W4226400568A5050002740 @default.
- W4226400568 hasAuthorship W4226400568A5085967185 @default.