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- W4226526459 abstract "A new class of stable four-coordinated benzotriazole-borane compounds was developed via gold-catalyzed alkyne hydroboration. The application of polymeric (BH2CN) n reagent gave the formation of cyano-amine-boranes (CAB) complexes with less basic N-heterocyclic amines and anilines. Various new CABs were investigated in catalytic hydroboration to synthesize N-B cycles. The 1,2,3-benzotriazoles were identified as the only feasible N-source, giving the four coordinated borane N-B cycles (BTAB) in excellent yields (up to 90%) with good functional group tolerability. This new class of polycyclic N-B compounds showed excellent stability toward acid, base, high temperature, and photo-irradiation. The facile synthesis, excellent stability, strong and tunable fluorescence emission make BTAB interesting new fluorescent probes for future chemical and biological applications." @default.
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- W4226526459 date "2022-01-01" @default.
- W4226526459 modified "2023-10-02" @default.
- W4226526459 title "Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission" @default.
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- W4226526459 doi "https://doi.org/10.1039/d2sc01103d" @default.
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