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- W42276119 abstract "Linar elution retention volume data have been acquired for alumina as adsorbent. Solute structure, eluent type, and alumina water deactivation have been varied over wide ranges, and the results semiquantitatively correlated in terms of a physical model. Adsorbent deactivation by water is shown to cause progressive reduction in the number of adsorption sites, with the remaining sites being weaker, but partition effects appear unimportant for 0–5% H2O-Al2O3. Solute adsorption free energy has been found to be linear function of adsorbent activity. A corollary of this observation is the “constant eluent non-crossing rule”: for a given eluent, solute separation order is unchanged as adsorbent activity is varied. For certain chromatographic system and solutes, retention volumes can be quantitatively predicted." @default.
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- W42276119 date "1961-01-01" @default.
- W42276119 modified "2023-09-27" @default.
- W42276119 title "Linear elution adsorption chromatography" @default.
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- W42276119 doi "https://doi.org/10.1016/s0021-9673(61)80214-8" @default.
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