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- W4229011714 abstract "Conventionally inaccessible end-functionalized vinyl polymers were synthesized via orthogonal side-chain replacement for terminal and repeating units of poly(alkenyl boronate)s. A terminal-defined polymer of isopropenyl boronic acid pinacol ester (IPBpin) was synthesized via RAFT polymerization, and subsequent cobalt (Co)-catalyzed end olefination afforded the polymer carrying the C(sp2)-B bond at the terminal and the C(sp3)-B bond in repeating units. Herein, the terminal C(sp2)-B bond was selectively transformable via palladium (Pd)-catalyzed Suzuki-Miyaura cross coupling, and subsequent transformation of the repeating C(sp3)-B unit gave the poly(α-methyl vinyl alcohol) [poly(MVA)] bearing various functional groups at the terminal. The boron-based stepwise polymer reaction thus overcame the synthetic difficulty of the end-functionalized poly(MVA), which is ascribed to the poor polymerization ability of the corresponding acetate monomer, i.e., isopropenyl acetate." @default.
- W4229011714 created "2022-05-08" @default.
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- W4229011714 date "2022-05-04" @default.
- W4229011714 modified "2023-10-17" @default.
- W4229011714 title "Orthogonal C–B Bond Transformation as an Approach for Versatile Synthesis of End-Functionalized Polymers" @default.
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- W4229011714 doi "https://doi.org/10.1021/acsmacrolett.2c00207" @default.
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