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- W4229021552 abstract "The utility of 2-diphenylphosphoryloxy-1,3-dienes for the construction of substituted six-membered nitrogen heterocycles is presented. These dienes undergo boron trifluoride-promoted aza-Diels-Alder reactions when reacted with imines or related species formed in situ using aldehydes and amine derivatives. The stability of the dienes allows this three-component reaction to be carried out with no special precautions to eliminate water or air. Thirty-one examples of this process are presented. The usefulness of the enol phosphate functional group is highlighted in further reactions after the cycloaddition step to generate functionalized piperidenes or pyridines." @default.
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- W4229021552 date "2022-06-09" @default.
- W4229021552 modified "2023-10-16" @default.
- W4229021552 title "Utility of 2‐Diphenylphosphoryloxy‐1,3‐Dienes in Multicomponent Hetero‐Diels–Alder Reactions to Construct Functionalized Six‐Membered Nitrogen Heterocycles" @default.
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- W4229021552 doi "https://doi.org/10.1002/chem.202201328" @default.
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