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- W4229027886 abstract "We report the synthesis of the double perovskite La 2 FeMnO 6 and a complete characterization of this system by using X-ray diffraction, Raman and Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), vibrating sample magnetometer, Mossbauer spectroscopy and lattice dynamic calculations. The ambient structure of the La 2 FeMnO 6 was well refined using monoclinic system and P 2 1 / n -space group, with two formulas per unit cell (Z = 2). SEM reveals that the sample is formed by particles with quasi-spherical morphology, randomly distributed in clusters. The investigation by Mössbauer spectroscopy identified that the incorporation of iron atoms occurred successfully in the analyzed structure since two paramagnetic phases were identified. The magnetization versus applied field (MxH) curve of La 2 FeMnO 6 at room temperature is discussed. The LFMO double perovskite EPR spectrum indicates the coexistence of paramagnetic resonance (PM) and antiferromagnetic resonance (AFM), being a strong indication of the coexistence of PM and AFM clusters. Moreover, vibrational properties were calculated using a rigid ion model in order to assign the experimental Raman and infrared bands. All these results making the La 2 FeMnO 6 an interesting material with practical applications and for the scientific investigations. • Synthesis and characterization of the double perovskite La 2 FeMnO 6 system. • Vibrational properties of the La 2 FeMnO 6 at room temperature. • Lattice dynamic calculations based on a rigid ion model. • The magnetization versus applied field (MxH) curve of La2FeMnO6 at room temperature." @default.
- W4229027886 created "2022-05-08" @default.
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- W4229027886 date "2022-08-01" @default.
- W4229027886 modified "2023-10-15" @default.
- W4229027886 title "Structural, vibrational and magnetic properties of monoclinic La2FeMnO6 double perovskite" @default.
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- W4229027886 doi "https://doi.org/10.1016/j.vacuum.2022.111140" @default.
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