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- W4229041054 abstract "Abstract Herein we report the electrochemical generation of a mononuclear Mn III (OO) (peroxo) complex supported on a dpaq ligand (dpaq=2‐(bis(pyridin‐2‐ylmethyl)amino)‐N‐(quinolin‐8‐yl)acetamide) for the first time, and its reactivity in N,N ‐dimethylformamide. The formation of the Mn III (dpaq)(OO) complex is probed by low temperature electronic absorption spectro‐electrochemistry experiments. An analysis of the reduction of the Mn III (dpaq)(OO) complex is carried out combining cyclic voltammetry and simulations. The involvement of a Mn II (dpaq)(OOH) complex is proposed based on CV data and is corroborated by DFT computations." @default.
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- W4229041054 date "2022-05-05" @default.
- W4229041054 modified "2023-10-18" @default.
- W4229041054 title "Electrochemical Formation and Reactivity of a Mn‐Peroxo Complex Bearing an Amido N5 Ligand" @default.
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- W4229041054 doi "https://doi.org/10.1002/celc.202200112" @default.
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