Matches in SemOpenAlex for { <https://semopenalex.org/work/W4229062014> ?p ?o ?g. }
- W4229062014 endingPage "124420" @default.
- W4229062014 startingPage "124420" @default.
- W4229062014 abstract "Hitherto, the development of Pt free bifunctional electrocatalyst for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) is necessary for the advancement of sustainable and cost-effective solutions for energy conversion and storage technology. In this direction, herein we elucidated the usage of N doped sp2 hybridized carbon framework (N-CF) as a metal-free electrocatalyst for ORR and HER. This work inspects the effect of N doping that converts a hybrid structure of CF {Norbornane or bicyclo [2], [2], [1] heptane structure} into planar N-CF. A series of N-doped CF with different doping concentrations has been prepared using a facile and cost-effective technique. This robust electrocatalysts exhibits a promotional effect in the activity, porosity, thermal and electrochemical stability for the ORR and HER reactions. A rich delocalized electronic density of the sp2 bounded N species helps in modulating antibonding state of molecular oxygen and facilitates the breakage of OO bond in ORR. It also promotes proton adsorption via bonding between proton and valence electron rich catalyst surface to aid HER. The research sought to investigate the employability of N-CF for fabricating sustainable energy devices with electrocatalyst possessing multiple electrocatalytic activities for ORR and HER. Density Functional Theory (DFT) computations reveals that active sites for HER are carbon atom located at the edge close to pyrrolic nitrogen and adjacent to graphitic nitrogen dopants." @default.
- W4229062014 created "2022-05-08" @default.
- W4229062014 creator A5019352224 @default.
- W4229062014 creator A5042085418 @default.
- W4229062014 creator A5068856731 @default.
- W4229062014 creator A5069648223 @default.
- W4229062014 creator A5084270712 @default.
- W4229062014 date "2022-09-01" @default.
- W4229062014 modified "2023-10-16" @default.
- W4229062014 title "Norbornane derived N-doped sp2 carbon framework as an efficient electrocatalyst for oxygen reduction reaction and hydrogen evolution reaction" @default.
- W4229062014 cites W1893178317 @default.
- W4229062014 cites W1966430867 @default.
- W4229062014 cites W1970839559 @default.
- W4229062014 cites W1976450881 @default.
- W4229062014 cites W1978648082 @default.
- W4229062014 cites W1979396951 @default.
- W4229062014 cites W1982860178 @default.
- W4229062014 cites W1987205935 @default.
- W4229062014 cites W1988133629 @default.
- W4229062014 cites W1989316650 @default.
- W4229062014 cites W2001000845 @default.
- W4229062014 cites W2002487156 @default.
- W4229062014 cites W2004316221 @default.
- W4229062014 cites W2007180790 @default.
- W4229062014 cites W2009901571 @default.
- W4229062014 cites W2024817672 @default.
- W4229062014 cites W2026291554 @default.
- W4229062014 cites W2039973450 @default.
- W4229062014 cites W2041471143 @default.
- W4229062014 cites W2048812651 @default.
- W4229062014 cites W2050305404 @default.
- W4229062014 cites W2050729150 @default.
- W4229062014 cites W2054311870 @default.
- W4229062014 cites W2062287652 @default.
- W4229062014 cites W2071301087 @default.
- W4229062014 cites W2074466573 @default.
- W4229062014 cites W2077762406 @default.
- W4229062014 cites W2080552958 @default.
- W4229062014 cites W2082388184 @default.
- W4229062014 cites W2085494254 @default.
- W4229062014 cites W2091938741 @default.
- W4229062014 cites W2100647938 @default.
- W4229062014 cites W2105775129 @default.
- W4229062014 cites W2116382224 @default.
- W4229062014 cites W2117061190 @default.
- W4229062014 cites W2119989570 @default.
- W4229062014 cites W2129905913 @default.
- W4229062014 cites W2130460345 @default.
- W4229062014 cites W2132827642 @default.
- W4229062014 cites W2132921900 @default.
- W4229062014 cites W2146849157 @default.
- W4229062014 cites W2155836566 @default.
- W4229062014 cites W2163409681 @default.
- W4229062014 cites W2171898868 @default.
- W4229062014 cites W2260789390 @default.
- W4229062014 cites W2346966993 @default.
- W4229062014 cites W2392428528 @default.
- W4229062014 cites W2480122429 @default.
- W4229062014 cites W2510191723 @default.
- W4229062014 cites W2517538953 @default.
- W4229062014 cites W2551937345 @default.
- W4229062014 cites W2594888243 @default.
- W4229062014 cites W2603259803 @default.
- W4229062014 cites W2607644016 @default.
- W4229062014 cites W2610550884 @default.
- W4229062014 cites W2726465153 @default.
- W4229062014 cites W2767495433 @default.
- W4229062014 cites W2771377027 @default.
- W4229062014 cites W2781885247 @default.
- W4229062014 cites W2783148362 @default.
- W4229062014 cites W2800747367 @default.
- W4229062014 cites W2887407475 @default.
- W4229062014 cites W2887904202 @default.
- W4229062014 cites W2899399663 @default.
- W4229062014 cites W2905218447 @default.
- W4229062014 cites W2907711813 @default.
- W4229062014 cites W2908851900 @default.
- W4229062014 cites W2945874953 @default.
- W4229062014 cites W2980691365 @default.
- W4229062014 cites W2982677825 @default.
- W4229062014 cites W2991400801 @default.
- W4229062014 cites W2998178396 @default.
- W4229062014 cites W3002609229 @default.
- W4229062014 cites W3004642104 @default.
- W4229062014 cites W3009755944 @default.
- W4229062014 cites W3014497499 @default.
- W4229062014 cites W3016344720 @default.
- W4229062014 cites W3022673214 @default.
- W4229062014 cites W3027369404 @default.
- W4229062014 cites W3034317218 @default.
- W4229062014 cites W3035927979 @default.
- W4229062014 cites W3036747057 @default.
- W4229062014 cites W3043132186 @default.
- W4229062014 cites W3048702673 @default.
- W4229062014 cites W3081187186 @default.
- W4229062014 cites W3093486306 @default.
- W4229062014 cites W3098735050 @default.
- W4229062014 cites W3106354956 @default.