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• W4229074039 abstract "In a ball mill, FeBr3-catalyzed intramolecular amidations lead to 3,4-dihydro-2(1H)-quinolinones in good to almost quantitative yields. The reactions do not require a solvent and are easy to perform. No additional ligand is needed for the iron catalyst. Both 4-substituted aryl and β-substituted dioxazolones provide products with high selectivity. Mechanistically, an electrophilic spirocyclization followed by C−C migration explains the formation of rearranged products." @default.
• W4229074039 created "2022-05-08" @default.
• W4229074039 creator A5007308411 @default.
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• W4229074039 creator A5090263634 @default.
• W4229074039 date "2022-06-10" @default.
• W4229074039 modified "2023-10-03" @default.
• W4229074039 title "Iron‐Catalyzed Intramolecular Arene C(sp ² )−H Amidations under Mechanochemical Conditions" @default.
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• W4229074039 doi "https://doi.org/10.1002/ange.202204874" @default.
• W4229074039 hasPublicationYear "2022" @default.
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