FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4229378032> ?p ?o ?g. }

• W4229378032 abstract "Abstract High‐voltage Li ion batteries are compromised by lower cycle life due to enhanced degradation of cathode material, for example LiNi 0.5 Co 0.2 Mn 0.3 O 2 (NCM523). Crucial part is the initiated electrode crosstalk, that is transition metal (TM) dissolution from the cathode and subsequent deposition on the anode, as it forces formation of high surface area lithium, capacity losses and risk of Li dendrite penetration, finally leading to an abrupt end‐of‐life (=rollover failure). Hence, suppression of this failure cascade is the pivotal strategy to prolong cycle life. A pragmatic approach was presented: the electrolyte manipulation towards formation/presence of fluorophosphates, as they effectively suppressed electrode crosstalk through TM scavenging. Either, they could be intrinsically formed, e. g. by elimination of ethylene carbonate (EC) solvent (=EC‐free electrolyte), or simply externally added, e. g . using (good‐soluble) lithium difluorophosphate electrolyte additive. Their effectiveness was demonstrated for conventional EC‐based and EC‐free electrolytes at limiting conditions (4.5 and 4.6 V, respectively). In parallel to supportive approach combinations (e. g. coating), also destructive combinations were highlighted, that is approaches, which even decrease the fluorophosphate content, e. g. vinylene carbonate additive in EC‐free electrolytes. Finally, by demonstrating the value of (concentration‐optimized) fluorophosphates, appropriate benchmark electrolyte formulations for high‐voltage LIBs were discussed." @default.
• W4229378032 created "2022-05-10" @default.
• W4229378032 creator A5000203192 @default.
• W4229378032 creator A5000507779 @default.
• W4229378032 creator A5017984605 @default.
• W4229378032 creator A5028797776 @default.
• W4229378032 creator A5043318938 @default.
• W4229378032 creator A5052399953 @default.
• W4229378032 creator A5052442441 @default.
• W4229378032 creator A5056611850 @default.
• W4229378032 creator A5060340757 @default.
• W4229378032 creator A5091432319 @default.
• W4229378032 date "2022-05-31" @default.
• W4229378032 modified "2023-09-25" @default.
• W4229378032 title "Suppressing Electrode Crosstalk and Prolonging Cycle Life in High‐Voltage Li Ion Batteries: Pivotal Role of Fluorophosphates in Electrolytes" @default.
• W4229378032 cites W2005140386 @default.
• W4229378032 cites W2006188180 @default.
• W4229378032 cites W2022395008 @default.
• W4229378032 cites W2038807397 @default.
• W4229378032 cites W2044005487 @default.
• W4229378032 cites W2069786258 @default.
• W4229378032 cites W2075496316 @default.
• W4229378032 cites W2136822440 @default.
• W4229378032 cites W2147494140 @default.
• W4229378032 cites W2153137964 @default.
• W4229378032 cites W2166851515 @default.
• W4229378032 cites W2169211003 @default.
• W4229378032 cites W2171745759 @default.
• W4229378032 cites W2223429084 @default.
• W4229378032 cites W2263500971 @default.
• W4229378032 cites W2513747533 @default.
• W4229378032 cites W2546433024 @default.
• W4229378032 cites W2552166594 @default.
• W4229378032 cites W2561118707 @default.
• W4229378032 cites W2562433809 @default.
• W4229378032 cites W2569358455 @default.
• W4229378032 cites W2593681241 @default.
• W4229378032 cites W2608184464 @default.
• W4229378032 cites W2612843351 @default.
• W4229378032 cites W2620692108 @default.
• W4229378032 cites W2622203992 @default.
• W4229378032 cites W2726997148 @default.
• W4229378032 cites W2749315824 @default.
• W4229378032 cites W2792717965 @default.
• W4229378032 cites W2801187234 @default.
• W4229378032 cites W2802844213 @default.
• W4229378032 cites W2807429901 @default.
• W4229378032 cites W2889901449 @default.
• W4229378032 cites W2890097323 @default.
• W4229378032 cites W2900208389 @default.
• W4229378032 cites W2911444641 @default.
• W4229378032 cites W2924836810 @default.
• W4229378032 cites W2944465212 @default.
• W4229378032 cites W2969971633 @default.
• W4229378032 cites W2980445549 @default.
• W4229378032 cites W2993488389 @default.
• W4229378032 cites W3007586926 @default.
• W4229378032 cites W3009325453 @default.
• W4229378032 cites W3013252775 @default.
• W4229378032 cites W3016150248 @default.
• W4229378032 cites W3017695943 @default.
• W4229378032 cites W3023435578 @default.
• W4229378032 cites W3033106394 @default.
• W4229378032 cites W3042943246 @default.
• W4229378032 cites W3044929321 @default.
• W4229378032 cites W3080472559 @default.
• W4229378032 cites W3088069738 @default.
• W4229378032 cites W3122651489 @default.
• W4229378032 cites W3128697756 @default.
• W4229378032 cites W3134357390 @default.
• W4229378032 cites W3137646107 @default.
• W4229378032 cites W3148147015 @default.
• W4229378032 cites W3191456090 @default.
• W4229378032 cites W3195970024 @default.
• W4229378032 cites W3216423940 @default.
• W4229378032 doi "https://doi.org/10.1002/celc.202200469" @default.
• W4229378032 hasPublicationYear "2022" @default.
• W4229378032 type Work @default.
• W4229378032 citedByCount "6" @default.
• W4229378032 countsByYear W42293780322022 @default.
• W4229378032 countsByYear W42293780322023 @default.
• W4229378032 crossrefType "journal-article" @default.
• W4229378032 hasAuthorship W4229378032A5000203192 @default.
• W4229378032 hasAuthorship W4229378032A5000507779 @default.
• W4229378032 hasAuthorship W4229378032A5017984605 @default.
• W4229378032 hasAuthorship W4229378032A5028797776 @default.
• W4229378032 hasAuthorship W4229378032A5043318938 @default.
• W4229378032 hasAuthorship W4229378032A5052399953 @default.
• W4229378032 hasAuthorship W4229378032A5052442441 @default.
• W4229378032 hasAuthorship W4229378032A5056611850 @default.
• W4229378032 hasAuthorship W4229378032A5060340757 @default.
• W4229378032 hasAuthorship W4229378032A5091432319 @default.
• W4229378032 hasBestOaLocation W42293780321 @default.
• W4229378032 hasConcept C127413603 @default.
• W4229378032 hasConcept C147789679 @default.
• W4229378032 hasConcept C171250308 @default.
• W4229378032 hasConcept C17525397 @default.
• W4229378032 hasConcept C179104552 @default.
• W4229378032 hasConcept C185592680 @default.
• W4229378032 hasConcept C192562407 @default.

• next