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- W4229443485 abstract "• One-pot α -ferrocenylalkylation of amino acid under acid-free conditions. • Ferrocenylalkylation via an intermediate formation of α -ferrocenylalkyl carbonates. • Regioselective α -ferrocenylalkylation of amino acid esters at the amino group. • Diastereoselective ferrocenylalkylation with (S)-(+)-α-ferrocenylethanol. The preparation of N -( α -ferrocenylalkyl) amino acid esters under neutral conditions by the reaction of in situ generated ( α -ferrocenylalkyl)carbonates with amino acid esters is described. The method allows regioselective one-pot alkylation of a series of amino acid esters at the amino group, as well as diastereoselective preparation of ferrocenylalkyl substituted amino acid esters from ( S )-(+)- α -ferrocenylethanol." @default.
- W4229443485 created "2022-05-11" @default.
- W4229443485 creator A5051064425 @default.
- W4229443485 date "2022-08-01" @default.
- W4229443485 modified "2023-09-26" @default.
- W4229443485 title "One-pot preparation of N-(α-ferrocenylalkyl) substituted amino acid esters under acid-free conditions" @default.
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- W4229443485 doi "https://doi.org/10.1016/j.jorganchem.2022.122384" @default.
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