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• W4229446265 abstract "Carbon monoxide-releasing molecules (CORMs) can offer a safer alternative to CO delivery than the use of CO gas cylinders. Upon treatment with an amine base, S-aryl thioformates (thioCORMates) release CO nearly quantitatively at room temperature, a gas which can then be harnessed for carbonylative cross-coupling, biological study, or inorganic synthesis. These bench-stable molecules are easily synthesized from the corresponding thiophenol and can be electronically tuned to release CO at different rates-from less than 1 min to greater than 1 h-offering a practical alternative to existing CORM technology. Finally, isotopically labeled 13 CO can be conveniently generated and used, with the thioCORMate synthesized from 13 C-formic acid." @default.
• W4229446265 created "2022-05-11" @default.
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• W4229446265 date "2022-06-07" @default.
• W4229446265 modified "2023-10-17" @default.
• W4229446265 title "ThioCORMates: Tunable and Cost‐Effective Carbon Monoxide‐Releasing Molecules" @default.
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• W4229446265 doi "https://doi.org/10.1002/chem.202201326" @default.
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