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• W4229448928 endingPage "734" @default.
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• W4229448928 abstract "Self-assembling molecular structures responding to light stimulus are appealing for applications as sensing and drug delivery. Supramolecular nanotubes have a relevant potential in nanotechnology as they can be used to encapsulate different loads like drugs, biological macromolecules, and nanomaterials. In addition, they are suitable elements for novel supracolloidal materials. Structural responses of supramolecular nanotubes to non-invasive stimuli are very much desired to enable controlled release of the encapsulated guests and to provide these recently developed new materials with an external trigger. Here, we describe the formation of well-defined, single wall tubules that interconvert into twisted ribbons upon UV-light exposure in aqueous environment. The structures are provided by self-assembly of an azobenzene substituted cholic acid, a biological surfactant belonging to the family of bile acids. The azobenzene group allows for the light responsiveness of the molecular packing. Concurrently the steroidal moieties assure both chiral features and extensive hydrophobic interactions for time and temperature resistant aggregates.The molecular packing interconversion was followed by circular dichroism. Microscopy, small angle X-ray scattering and light scattering measurements demonstrated the drastic morphological variation upon irradiation. A model of the molecular arrangement within the tubular walls was suggested based on the circular dichroism spectra simulation.Innovatively, the molecular design reported in our work allows for encoding in the same light responsive system multiple desirable features (e.g. bio-origin, temperature resistance and chirality of the aggregates). Such combination of properties, never reported before for a single molecule, might be relevant for the realization of robust, stimuli-responsive bio-vectors." @default.
• W4229448928 created "2022-05-11" @default.
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• W4229448928 date "2022-10-01" @default.
• W4229448928 modified "2023-10-16" @default.
• W4229448928 title "Bioderived, chiral and stable 1-dimensional light-responsive nanostructures: Interconversion between tubules and twisted ribbons" @default.
• W4229448928 cites W1184977391 @default.
• W4229448928 cites W1879612728 @default.
• W4229448928 cites W1965141624 @default.
• W4229448928 cites W1968706269 @default.
• W4229448928 cites W1972653995 @default.
• W4229448928 cites W1979250134 @default.
• W4229448928 cites W1981194462 @default.
• W4229448928 cites W2003424313 @default.
• W4229448928 cites W2010216133 @default.
• W4229448928 cites W2011315553 @default.
• W4229448928 cites W2012730115 @default.
• W4229448928 cites W2013996015 @default.
• W4229448928 cites W2017215270 @default.
• W4229448928 cites W2022521530 @default.
• W4229448928 cites W2023439172 @default.
• W4229448928 cites W2024481063 @default.
• W4229448928 cites W2027297934 @default.
• W4229448928 cites W2028046413 @default.
• W4229448928 cites W2029349029 @default.
• W4229448928 cites W2037288322 @default.
• W4229448928 cites W2043575681 @default.
• W4229448928 cites W2045402895 @default.
• W4229448928 cites W2048046519 @default.
• W4229448928 cites W2052686202 @default.
• W4229448928 cites W2053936440 @default.
• W4229448928 cites W2056073835 @default.
• W4229448928 cites W2060030489 @default.
• W4229448928 cites W2066146371 @default.
• W4229448928 cites W2070963350 @default.
• W4229448928 cites W2078410144 @default.
• W4229448928 cites W2084754885 @default.
• W4229448928 cites W2087203122 @default.
• W4229448928 cites W2093275796 @default.
• W4229448928 cites W2101755751 @default.
• W4229448928 cites W2106824077 @default.
• W4229448928 cites W2112306526 @default.
• W4229448928 cites W2127463784 @default.
• W4229448928 cites W2133797478 @default.
• W4229448928 cites W2136104516 @default.
• W4229448928 cites W2142515672 @default.
• W4229448928 cites W2145128986 @default.
• W4229448928 cites W2163197158 @default.
• W4229448928 cites W2165852855 @default.
• W4229448928 cites W2287978221 @default.
• W4229448928 cites W2293332446 @default.
• W4229448928 cites W2312718901 @default.
• W4229448928 cites W2313363457 @default.
• W4229448928 cites W2322612119 @default.
• W4229448928 cites W2330351143 @default.
• W4229448928 cites W2331539235 @default.
• W4229448928 cites W2333663327 @default.
• W4229448928 cites W2550948030 @default.
• W4229448928 cites W2552482610 @default.
• W4229448928 cites W2740112542 @default.
• W4229448928 cites W2765820862 @default.
• W4229448928 cites W2780825361 @default.
• W4229448928 cites W2784272855 @default.
• W4229448928 cites W2790025175 @default.
• W4229448928 cites W2792425182 @default.
• W4229448928 cites W2809847361 @default.
• W4229448928 cites W2811425716 @default.
• W4229448928 cites W2884891347 @default.
• W4229448928 cites W2889774332 @default.
• W4229448928 cites W2891949334 @default.
• W4229448928 cites W2899253016 @default.
• W4229448928 cites W2954084898 @default.
• W4229448928 cites W2980759515 @default.
• W4229448928 cites W3137163681 @default.
• W4229448928 cites W3176643108 @default.
• W4229448928 cites W3194485894 @default.
• W4229448928 cites W4211107160 @default.
• W4229448928 cites W4214649380 @default.
• W4229448928 cites W4233037007 @default.
• W4229448928 cites W4235710165 @default.
• W4229448928 cites W4238536802 @default.
• W4229448928 cites W4244506205 @default.
• W4229448928 cites W4251986784 @default.
• W4229448928 doi "https://doi.org/10.1016/j.jcis.2022.05.025" @default.
• W4229448928 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35605451" @default.
• W4229448928 hasPublicationYear "2022" @default.
• W4229448928 type Work @default.

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