Matches in SemOpenAlex for { <https://semopenalex.org/work/W4229448977> ?p ?o ?g. }
- W4229448977 endingPage "120593" @default.
- W4229448977 startingPage "120593" @default.
- W4229448977 abstract "Unravelling synthesis-morphology-performance relations of thin-film polyamide (PA) selective layers prepared via interfacial polymerization (IP) is essential for tailor-made membrane design. Here, an approach is outlined, which links synthesis and morphology in terms of the interfacial stability of a system undergoing IP, with the notion that a transition from a stable to an unstable state corresponds to a morphological shift of the resultant film, e.g., from smooth to crumpled. Within the proposed framework, physical parameters related to a variety of synthesis conditions are identified and classified based on their effect on two defined criteria: the polymer formation rate and/or the system susceptibility to instability. A conceptual phase diagram maps the morphological regimes with respect to the relevant parameter space. Our analysis, based on available literature data, illustrates how PA morphology, as observed in published SEM images, transitions from smooth to crumpled, exhibits a remarkable correlation with the defined parameter space, and hereby the stability of the system. Re-thinking experimental results in this manner highlights not only the underlying physics, but also identifies potential pitfalls when variations of synthesis conditions result in conflicting effects. Our motivation is to encourage experimental design based on the developed framework supplemented by theoretical quantification, which will strengthen the fundamental understanding of IP for a given chemistry, with the goal of providing a clear physical toolbox for IP-based membrane design." @default.
- W4229448977 created "2022-05-11" @default.
- W4229448977 creator A5049473398 @default.
- W4229448977 creator A5056884819 @default.
- W4229448977 creator A5059389982 @default.
- W4229448977 creator A5073629038 @default.
- W4229448977 date "2022-08-01" @default.
- W4229448977 modified "2023-10-11" @default.
- W4229448977 title "Re-thinking polyamide thin film formation: How does interfacial destabilization dictate film morphology?" @default.
- W4229448977 cites W118417999 @default.
- W4229448977 cites W1513798492 @default.
- W4229448977 cites W1762309035 @default.
- W4229448977 cites W1822614884 @default.
- W4229448977 cites W1974455685 @default.
- W4229448977 cites W1975627007 @default.
- W4229448977 cites W1977255921 @default.
- W4229448977 cites W1980449311 @default.
- W4229448977 cites W1986065639 @default.
- W4229448977 cites W1999912496 @default.
- W4229448977 cites W2012008704 @default.
- W4229448977 cites W2012270576 @default.
- W4229448977 cites W2016625509 @default.
- W4229448977 cites W2018117261 @default.
- W4229448977 cites W2018669669 @default.
- W4229448977 cites W2019804612 @default.
- W4229448977 cites W2023008288 @default.
- W4229448977 cites W2026256593 @default.
- W4229448977 cites W2029290800 @default.
- W4229448977 cites W2034026260 @default.
- W4229448977 cites W2037337872 @default.
- W4229448977 cites W2046833784 @default.
- W4229448977 cites W2047253801 @default.
- W4229448977 cites W2048636247 @default.
- W4229448977 cites W2051639998 @default.
- W4229448977 cites W2053400299 @default.
- W4229448977 cites W2055638681 @default.
- W4229448977 cites W2058901438 @default.
- W4229448977 cites W2063054674 @default.
- W4229448977 cites W2065417439 @default.
- W4229448977 cites W2072307171 @default.
- W4229448977 cites W2073983852 @default.
- W4229448977 cites W2076973118 @default.
- W4229448977 cites W2077290609 @default.
- W4229448977 cites W2082507698 @default.
- W4229448977 cites W2088453239 @default.
- W4229448977 cites W2090538517 @default.
- W4229448977 cites W2091045346 @default.
- W4229448977 cites W2091946969 @default.
- W4229448977 cites W2093097240 @default.
- W4229448977 cites W2098823895 @default.
- W4229448977 cites W2111243341 @default.
- W4229448977 cites W2150529726 @default.
- W4229448977 cites W2151124643 @default.
- W4229448977 cites W2163662378 @default.
- W4229448977 cites W2170804474 @default.
- W4229448977 cites W2171749040 @default.
- W4229448977 cites W2188497676 @default.
- W4229448977 cites W2239262139 @default.
- W4229448977 cites W2296406830 @default.
- W4229448977 cites W2320794742 @default.
- W4229448977 cites W2332136976 @default.
- W4229448977 cites W2513084864 @default.
- W4229448977 cites W2564604623 @default.
- W4229448977 cites W2565290952 @default.
- W4229448977 cites W2576579942 @default.
- W4229448977 cites W2593184123 @default.
- W4229448977 cites W2608453901 @default.
- W4229448977 cites W2612989517 @default.
- W4229448977 cites W2624487967 @default.
- W4229448977 cites W2626055502 @default.
- W4229448977 cites W2639397622 @default.
- W4229448977 cites W2664227071 @default.
- W4229448977 cites W2725570054 @default.
- W4229448977 cites W2740580419 @default.
- W4229448977 cites W2749696343 @default.
- W4229448977 cites W2766840064 @default.
- W4229448977 cites W2782560167 @default.
- W4229448977 cites W2785951653 @default.
- W4229448977 cites W2788570137 @default.
- W4229448977 cites W2789798954 @default.
- W4229448977 cites W2796127341 @default.
- W4229448977 cites W2803058542 @default.
- W4229448977 cites W2883069024 @default.
- W4229448977 cites W2885183401 @default.
- W4229448977 cites W2891784280 @default.
- W4229448977 cites W2901282447 @default.
- W4229448977 cites W2905076512 @default.
- W4229448977 cites W2910067397 @default.
- W4229448977 cites W2912383661 @default.
- W4229448977 cites W2936762821 @default.
- W4229448977 cites W2942313918 @default.
- W4229448977 cites W2946778620 @default.
- W4229448977 cites W2949092283 @default.
- W4229448977 cites W2953340085 @default.
- W4229448977 cites W2966522325 @default.
- W4229448977 cites W2975794953 @default.
- W4229448977 cites W2997332132 @default.
- W4229448977 cites W3004615938 @default.