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- W4229551601 abstract "Reduktive Spaltung eines Diphosphid-verbrückten Komplexes mit Natriumamalgam führt zum Niobkomplex [PNb(N[Np]Ar)3]− (siehe Bild; Np=Neopentyl, Ar=3,5-Me2C6H3) mit einem terminalen Phosphidoliganden, der formal über eine Nb-P-Dreifachbindung gebunden ist. Das Anion reagiert am nucleophilen Phosphoratom mit ClPtBu2 oder ClPPh2. Dabei entstehen die ersten η2-Phosphanylphosphiniden-Komplexe von frühen Übergangsmetallen. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2004/z52779_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4229551601 date "2004-02-11" @default.
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- W4229551601 title "Diorganophosphanylphosphinidenes as Complexed Ligands: Synthesis via an Anionic Terminal Phosphide of Niobium" @default.
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- W4229551601 doi "https://doi.org/10.1002/ange.200352779" @default.
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