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- W4229637350 abstract "The phosphanediides of the alkali metals, magnesium, and tin(n) oligomerize and form spherical cages. The degree of aggregation depends strongly on the steric demand of the trialkylsilyl substituents. The partial substitution of tin atoms in [SnPSitBu3]4 preserves the heterocubane structure, the general formula for these heterocubane structures being [MnSn4-n(PR)4] with n = 0, 1, 2, and 3. Homometallic cages of the heavier alkaline earth metals show the trigonal M2P3 bipyramid as the structure-dominating motif. These bipyramids can be combined via common faces thus leading to M3P4 cages. For the less reactive arsanediides an aggregation via common corners is also observed. Homoleptic phosphanediides of the heavy alkaline earth metals are unknown as yet." @default.
- W4229637350 created "2022-05-11" @default.
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- W4229637350 date "2003-09-26" @default.
- W4229637350 modified "2023-10-16" @default.
- W4229637350 title "Mutual Effects Between the Trialkylsilyl Substituents and the M <sub> <i>m</i> </sub> P <sub> <i>n</i> </sub> Cages of Phosphanediides (M = Mg, Ca, Sr, Ba, and Sn)" @default.
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- W4229637350 doi "https://doi.org/10.1002/9783527619924.ch49" @default.
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