Matches in SemOpenAlex for { <https://semopenalex.org/work/W4229667434> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W4229667434 abstract "In a previous study the trimer of rhenium tetracarbonyl was found to be diamagnetic, suggesting the presence of hydrogen in the compound. This was supported by chemical analysis, which indicated about one hydrogen per rhenium, and the compound was formulated as [Re(C0)4H] 3• Subsequently a proton resonance was observed on a broad line spectrometer. In the original work the infrared spectra were compared for the hydride and deuteride; cyclohexane solutions were used for the CO stretching region and KBr discs were used for the rest of the spectrum. Surprisingly, the spectra of the hydride and deuteride showed only minor differences, insufficient to confirm the presence of hydrogen. No evidence of a hydrogen stretching frequency was found. In the present work, the previously unobserved Raman spectra were measured for the hydride and deuteride . In the solid state ratber striking shifts were observed in the CO stretching region. Also there is some evidence for a metal-hydrogen stretching band at the rather low frequency of 1100 cm-1. In an attempt to support the interpretation of the Raman spectra more detailed infrared studies of the solid in KBr discs were made. The hope was to observe a metal-hydrogen stretching frequency and to explain the shifts in the CO stretching frequencies." @default.
- W4229667434 created "2022-05-11" @default.
- W4229667434 creator A5000634724 @default.
- W4229667434 creator A5025329199 @default.
- W4229667434 creator A5028781812 @default.
- W4229667434 date "1965-03-25" @default.
- W4229667434 modified "2023-09-27" @default.
- W4229667434 title "Raman Studies of Hydrido- and Deutero- Rhenium Tetracarbonyl Trimer" @default.
- W4229667434 doi "https://doi.org/10.2172/12683026" @default.
- W4229667434 hasPublicationYear "1965" @default.
- W4229667434 type Work @default.
- W4229667434 citedByCount "0" @default.
- W4229667434 crossrefType "report" @default.
- W4229667434 hasAuthorship W4229667434A5000634724 @default.
- W4229667434 hasAuthorship W4229667434A5025329199 @default.
- W4229667434 hasAuthorship W4229667434A5028781812 @default.
- W4229667434 hasBestOaLocation W42296674343 @default.
- W4229667434 hasConcept C113196181 @default.
- W4229667434 hasConcept C120665830 @default.
- W4229667434 hasConcept C121332964 @default.
- W4229667434 hasConcept C1276947 @default.
- W4229667434 hasConcept C147789679 @default.
- W4229667434 hasConcept C153642686 @default.
- W4229667434 hasConcept C158355884 @default.
- W4229667434 hasConcept C178790620 @default.
- W4229667434 hasConcept C179104552 @default.
- W4229667434 hasConcept C184779094 @default.
- W4229667434 hasConcept C185592680 @default.
- W4229667434 hasConcept C19449701 @default.
- W4229667434 hasConcept C2776403692 @default.
- W4229667434 hasConcept C2777961443 @default.
- W4229667434 hasConcept C2778237882 @default.
- W4229667434 hasConcept C2779546866 @default.
- W4229667434 hasConcept C40003534 @default.
- W4229667434 hasConcept C4839761 @default.
- W4229667434 hasConcept C505216180 @default.
- W4229667434 hasConcept C512968161 @default.
- W4229667434 hasConcept C54516573 @default.
- W4229667434 hasConcept C58364064 @default.
- W4229667434 hasConcept C62520636 @default.
- W4229667434 hasConcept C75473681 @default.
- W4229667434 hasConcept C8010536 @default.
- W4229667434 hasConceptScore W4229667434C113196181 @default.
- W4229667434 hasConceptScore W4229667434C120665830 @default.
- W4229667434 hasConceptScore W4229667434C121332964 @default.
- W4229667434 hasConceptScore W4229667434C1276947 @default.
- W4229667434 hasConceptScore W4229667434C147789679 @default.
- W4229667434 hasConceptScore W4229667434C153642686 @default.
- W4229667434 hasConceptScore W4229667434C158355884 @default.
- W4229667434 hasConceptScore W4229667434C178790620 @default.
- W4229667434 hasConceptScore W4229667434C179104552 @default.
- W4229667434 hasConceptScore W4229667434C184779094 @default.
- W4229667434 hasConceptScore W4229667434C185592680 @default.
- W4229667434 hasConceptScore W4229667434C19449701 @default.
- W4229667434 hasConceptScore W4229667434C2776403692 @default.
- W4229667434 hasConceptScore W4229667434C2777961443 @default.
- W4229667434 hasConceptScore W4229667434C2778237882 @default.
- W4229667434 hasConceptScore W4229667434C2779546866 @default.
- W4229667434 hasConceptScore W4229667434C40003534 @default.
- W4229667434 hasConceptScore W4229667434C4839761 @default.
- W4229667434 hasConceptScore W4229667434C505216180 @default.
- W4229667434 hasConceptScore W4229667434C512968161 @default.
- W4229667434 hasConceptScore W4229667434C54516573 @default.
- W4229667434 hasConceptScore W4229667434C58364064 @default.
- W4229667434 hasConceptScore W4229667434C62520636 @default.
- W4229667434 hasConceptScore W4229667434C75473681 @default.
- W4229667434 hasConceptScore W4229667434C8010536 @default.
- W4229667434 hasLocation W42296674341 @default.
- W4229667434 hasLocation W42296674342 @default.
- W4229667434 hasLocation W42296674343 @default.
- W4229667434 hasOpenAccess W4229667434 @default.
- W4229667434 hasPrimaryLocation W42296674341 @default.
- W4229667434 hasRelatedWork W1663069862 @default.
- W4229667434 hasRelatedWork W1973087998 @default.
- W4229667434 hasRelatedWork W2017551463 @default.
- W4229667434 hasRelatedWork W2025570563 @default.
- W4229667434 hasRelatedWork W2031791123 @default.
- W4229667434 hasRelatedWork W2067384221 @default.
- W4229667434 hasRelatedWork W2154239330 @default.
- W4229667434 hasRelatedWork W2382265818 @default.
- W4229667434 hasRelatedWork W4229667434 @default.
- W4229667434 hasRelatedWork W3106581363 @default.
- W4229667434 isParatext "false" @default.
- W4229667434 isRetracted "false" @default.
- W4229667434 workType "report" @default.