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- W4229697051 abstract "Publisher SummaryThis chapter describes high-silica zeolites with MTW framework topology. Based on their X-ray diffraction (XRD) patterns, several zeolites seem to be closely related, suggesting that they possess the same framework topology. They all are proprietary materials, denoted ZSM-12, NU-13, CZH-5, TEA-silicate or TPZ-3. For ZSM-12, the framework structure has been proposed and the computed XRD pattern can be compared with the experimental pattern. For zeolite NU-13, it is explicitly stated in the chapter that it is a member of the ZSM-12 family of zeolites. TEA-silicate is said to belong to a new class of crystalline metal organosilicates which are synthesized from reaction systems essentially free of aluminium-containing reagents. This is said to be in contrast to ZSM-12 zeolites, which are synthesized using the same organic structure-directing agent. Zeolite TPZ-3 is said to be related to ZSM-12 but has a much stronger XRD peak at 0.402 nm. It differs from Zeolite Socony Mobil Number 5 (ZSM-5) in the presence of a strong peak at 0.433 nm. The ultimate XRD pattern might eventually be composed of a ZSM-12-like material, kenyaite (k) and cristobalite (c), which could account for the differences in the number of lines and intensities. Some specific doublets observed in ZSM-12 are present in TPZ-3 as single lines, indicative of a higher symmetry." @default.
- W4229697051 created "2022-05-11" @default.
- W4229697051 date "1987-01-01" @default.
- W4229697051 modified "2023-09-26" @default.
- W4229697051 title "Chapter IX: High-Silica Zeolites with MTW Framework Topology." @default.
- W4229697051 cites W2063813878 @default.
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- W4229697051 doi "https://doi.org/10.1016/s0167-2991(09)60475-4" @default.
- W4229697051 hasPublicationYear "1987" @default.
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