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- W4229780488 abstract "A simple, new type of chiral sulfinamide monophosphines, the so-called Ming-Phos ligands, is reported; these ligands could be easily prepared from inexpensive and commercially available starting materials. The Ming-Phos ligands performed well in the enantioselective gold-catalyzed cycloaddition reaction of 2-(1-alkynyl)-alk-2-en-1-ones with nitrones. Both enantiomers of the products could be obtained in good yields and with excellent diastereo- and enantioselectivity through transformations that were catalyzed by gold complexes derived from two diastereomers of Ming-Phos ligand M5 (Ar=1-naphthyl)." @default.
- W4229780488 created "2022-05-11" @default.
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- W4229780488 date "2014-03-20" @default.
- W4229780488 modified "2023-10-07" @default.
- W4229780488 title "A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions" @default.
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- W4229780488 doi "https://doi.org/10.1002/ange.201401067" @default.
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