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- W4230111170 abstract "Abstract Aminocyclopropenium ions have raised much attention as organocatalysts and redox active polymers. However, the self‐assembly of amphiphilic aminocyclopropenium ions remains challenging. The first deltic ionic liquid crystals based on aminocyclopropenium ions have been developed. Differential scanning calorimetry, polarizing optical microscopy and X‐ray diffraction provided insight into the unique self‐assembly and nanosegregation of these liquid crystals. While the combination of small headgroups with linear p ‐alkoxyphenyl units led to bilayer‐type smectic mesophases, wedge‐shaped units resulted in columnar mesophases. Upon increasing the size and polyphilicity of the aminocyclopropenium headgroup, a lamellar phase was formed." @default.
- W4230111170 created "2022-05-11" @default.
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- W4230111170 date "2020-04-07" @default.
- W4230111170 modified "2023-09-26" @default.
- W4230111170 title "Self‐Assembly of Aminocyclopropenium Salts: En Route to Deltic Ionic Liquid Crystals" @default.
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- W4230111170 doi "https://doi.org/10.1002/ange.202000824" @default.
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