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- W4230195510 abstract "Abstract A room‐temperature‐stable crystalline cyclic (alkyl)(amino)nitrenium cation 2 features cationic nitrogen atom with a smaller HOMO–LUMO gap compared to that of a 1,2,3‐triazolium 5 (an N‐heterocyclic nitrenium cation). The low‐lying LUMO of 2 results in an enhanced electrophilicity, which allowed for the formation of Lewis adducts with neutral Lewis bases, such as Me 3 P, n Bu 3 P, and I i Pr. The N‐based Lewis acid 2 also forms an FLP with t Bu 3 P but subsequently reacts with (PrS) 2 to cleave the S−S bond. Both experimental and theoretical results suggest that the Lewis acidity of 2 is stronger than its N 3 analogues." @default.
- W4230195510 created "2022-05-11" @default.
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- W4230195510 date "2018-02-21" @default.
- W4230195510 modified "2023-10-04" @default.
- W4230195510 title "Nitrogen-Based Lewis Acids: Synthesis and Reactivity of a Cyclic (Alkyl)(Amino)Nitrenium Cation" @default.
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- W4230195510 doi "https://doi.org/10.1002/ange.201713118" @default.
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