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- W4230200532 abstract "Zero-valent palladium precatalysts containing rigid bidentate bis(arylimino)acenaphthene ligands (shown schematically) facilitate the highly stereoselective homogeneous catalytic hydrogenation of alkynes to (Z)-alkenes. Internal, terminal, aryl-substituted, and cyclic alkynes are suitable substrates, as are some enynes, which are chemoselectively hydrogenated to dienes. E=CO2Me; R1, R2=4-OCH3, 4-CH3, 2,6-(CH3)2." @default.
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- W4230200532 date "1999-12-16" @default.
- W4230200532 modified "2023-10-03" @default.
- W4230200532 title "Selective Homogeneous Palladium(0)-Catalyzed Hydrogenation of Alkynes to (Z)-Alkenes" @default.
- W4230200532 doi "https://doi.org/10.1002/(sici)1521-3773(19991216)38:24<3715::aid-anie3715>3.3.co;2-f" @default.
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