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- W4230208330 endingPage "4867" @default.
- W4230208330 startingPage "4864" @default.
- W4230208330 abstract "Abstract About 20 % of the ammonia production is used as the chemical feedstock for nitrogen‐containing chemicals. However, while synthetic nitrogen fixation at ambient conditions has had some groundbreaking contributions in recent years, progress for the direct conversion of N 2 into organic products remains limited and catalytic reactions are unknown. Herein, the rhenium‐mediated synthesis of acetonitrile using dinitrogen and ethyl triflate is presented. A synthetic cycle in three reaction steps with high individual isolated yields and recovery of the rhenium pincer starting complex is shown. The cycle comprises alkylation of a nitride that arises from N 2 splitting and subsequent imido ligand centered oxidation to nitrile via a 1‐azavinylidene (ketimido) intermediate. Different synthetic strategies for intra‐ and intermolecular imido ligand oxidation and associated metal reduction were evaluated that rely on simple proton, electron, and hydrogen‐atom transfer steps." @default.
- W4230208330 created "2022-05-11" @default.
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- W4230208330 date "2016-03-07" @default.
- W4230208330 modified "2023-10-18" @default.
- W4230208330 title "Conversion of Dinitrogen into Acetonitrile under Ambient Conditions" @default.
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- W4230208330 doi "https://doi.org/10.1002/ange.201600790" @default.
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