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• W4230271314 abstract "The reaction of lithium triisopropylsilylamide with (Me3Si)3CZnC1 yields tris(trimethylsilyl)methylzinc triisopropylsilylamide. The homologous phosphanide and arsanide give [(Me3Si)3CZn]2ESiiPr3 with E = P, As. Smaller substituents at the pentele atoms lead to the formation of zincates. Tetrakis(tetrahydrofuran-O)lithium bis[tris(trimethylsilyl)methylzinc] tris(anilide) is isolated from the metathesis reaction of lithium anilide and (MeCZnCl. The lithiation of Me3SiPH2 yields LiP(H)SiMe3; however, redistribution reactions lead also to LiPHz and LiP(SiMe3)z. The reaction of this mixture with (Me3Si)3CZnCI gives [(thf)4Li]'{[(Me3Si)3CZn], (p-Cl)(p3-PH)2)." @default.
• W4230271314 created "2022-05-11" @default.
• W4230271314 creator A5041033473 @default.
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• W4230271314 date "2000-01-17" @default.
• W4230271314 modified "2023-10-14" @default.
• W4230271314 title "Influence of the Steric Demand of Lithium Trialkylsilylamides, ‐Phosphanides and ‐Arsanides on the Metathesis Reaction with Tris(trimethylsilyl)methylzinc Chloride" @default.
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• W4230271314 doi "https://doi.org/10.1002/9783527619917.ch46" @default.
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