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- W4230272893 abstract "An unprecedented copper(I)-catalyzed vinylation of (donor)-acceptor diazo compounds with VinylBenziodoXolone reagents (VBX) as partners is reported. The transformation tolerates variation of both donor- and acceptor substituents on the diazo compounds, delivering the corresponding benzoylated allylic alcohol products in good to excellent yields. Through the development of a protocol for the synthesis of functionalized alkanes-, dienes- and enynes-substituted VBX reagents, a broad scope of substituents on the alkene could be accessed. The obtained products contain synthetically versatile functional groups, such as an aryl iodide, an ester and an allylic leaving group, enabling selective further modification." @default.
- W4230272893 created "2022-05-11" @default.
- W4230272893 creator A5008165586 @default.
- W4230272893 creator A5036715151 @default.
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- W4230272893 date "2019-03-27" @default.
- W4230272893 modified "2023-09-28" @default.
- W4230272893 title "Copper-Catalyzed Insertion of Diazo Compounds into Vinyl Hypervalent Iodine Reagents to Generate Allylic Esters" @default.
- W4230272893 doi "https://doi.org/10.26434/chemrxiv.7892513" @default.
- W4230272893 hasPublicationYear "2019" @default.
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